Oxidation of Alkenes by Water with H2 Liberation

Shan Tang, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

Abstract

Oxidation by water with H2 liberation is highly desirable, as it can serve as an environmentally friendly way for the oxidation of organic compounds. Herein, we report the oxidation of alkenes with water as the oxidant by using a catalyst combination of a dearomatized acridine-based PNP-Ru complex and indium(III) triflate. Compared to traditional Wacker-type oxidation, this transformation avoids the use of added chemical oxidants and liberates hydrogen gas as the only byproduct.

Original languageEnglish
Pages (from-to)5980-5984
Number of pages5
JournalJournal of the American Chemical Society
Volume142
Issue number13
DOIs
Publication statusPublished - Apr 1 2020

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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