Oxidative addition of Si-Cl bonds to electron-rich IrI complexes

Andrei A. Zlota, Felix Frolow, David Milstein

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

Original languageEnglish
Pages (from-to)1826-1827
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
Publication statusPublished - Jan 1 1989

ASJC Scopus subject areas

  • Molecular Medicine

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