Oxidative addition of Si-Cl bonds to electron-rich IrI complexes

Andrei A. Zlota, Felix Frolow, David Milstein

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

Original languageEnglish
Pages (from-to)1826-1827
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
Publication statusPublished - 1989

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Hydrides
Electrons

ASJC Scopus subject areas

  • Molecular Medicine

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Oxidative addition of Si-Cl bonds to electron-rich IrI complexes. / Zlota, Andrei A.; Frolow, Felix; Milstein, David.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 1989, p. 1826-1827.

Research output: Contribution to journal › Article

Zlota, AA, Frolow, F & Milstein, D 1989, 'Oxidative addition of Si-Cl bonds to electron-rich IrI complexes', Journal of the Chemical Society, Chemical Communications, no. 23, pp. 1826-1827. https://doi.org/10.1039/C39890001826
Zlota AA, Frolow F, Milstein D. Oxidative addition of Si-Cl bonds to electron-rich IrI complexes. Journal of the Chemical Society, Chemical Communications. 1989;(23):1826-1827. https://doi.org/10.1039/C39890001826
Zlota, Andrei A. ; Frolow, Felix ; Milstein, David. / Oxidative addition of Si-Cl bonds to electron-rich IrI complexes. In: Journal of the Chemical Society, Chemical Communications. 1989 ; No. 23. pp. 1826-1827.
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