Oxidative addition of Si-Cl bonds to electron-rich IrI complexes

Andrei A. Zlota; Felix Frolow; David Milstein

doi:10.1039/C39890001826

Oxidative addition of Si-Cl bonds to electron-rich Ir^I complexes

Andrei A. Zlota, Felix Frolow, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

Si-Cl bonds undergo facile, rarely observed oxidative addition to (C ₈H₁₄)Ir(PMe₃)₃Cl (1) to yield, when MeSiCl₃ is used, the crystallographically characterized mer-Ir(PMe₃)₃(Cl)₂(SiMeCl₂), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich Ir^I complexes with Me₃SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

Original language	English
Pages (from-to)	1826-1827
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39890001826
Publication status	Published - Jan 1 1989

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39890001826

Fingerprint Dive into the research topics of 'Oxidative addition of Si-Cl bonds to electron-rich Ir<sup>I</sup> complexes'. Together they form a unique fingerprint.

Cite this

Zlota, A. A., Frolow, F., & Milstein, D. (1989). Oxidative addition of Si-Cl bonds to electron-rich Ir^I complexes. Journal of the Chemical Society, Chemical Communications, (23), 1826-1827. https://doi.org/10.1039/C39890001826

@article{7adee24e23fe4b0d939f0a7d84fe6e60,

title = "Oxidative addition of Si-Cl bonds to electron-rich IrI complexes",

abstract = "Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.",

author = "Zlota, {Andrei A.} and Felix Frolow and David Milstein",

year = "1989",

month = jan,

day = "1",

doi = "10.1039/C39890001826",

language = "English",

pages = "1826--1827",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Oxidative addition of Si-Cl bonds to electron-rich IrI complexes

AU - Zlota, Andrei A.

AU - Frolow, Felix

AU - Milstein, David

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

AB - Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

UR - http://www.scopus.com/inward/record.url?scp=37049083731&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049083731&partnerID=8YFLogxK

U2 - 10.1039/C39890001826

DO - 10.1039/C39890001826

M3 - Article

SP - 1826

EP - 1827

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 23

ER -