Oxidative addition of Si-Cl bonds to electron-rich IrI complexes

Andrei A. Zlota; Felix Frolow; David Milstein

doi:10.1039/C39890001826

Oxidative addition of Si-Cl bonds to electron-rich Ir^I complexes

Andrei A. Zlota, Felix Frolow, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

54 Citations (Scopus)

Abstract

Si-Cl bonds undergo facile, rarely observed oxidative addition to (C ₈H₁₄)Ir(PMe₃)₃Cl (1) to yield, when MeSiCl₃ is used, the crystallographically characterized mer-Ir(PMe₃)₃(Cl)₂(SiMeCl₂), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich Ir^I complexes with Me₃SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

Original language	English
Pages (from-to)	1826-1827
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39890001826
Publication status	Published - Jan 1 1989

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ASJC Scopus subject areas

Molecular Medicine

Cite this

Zlota, A. A., Frolow, F., & Milstein, D. (1989). Oxidative addition of Si-Cl bonds to electron-rich Ir^I complexes. Journal of the Chemical Society, Chemical Communications, (23), 1826-1827. https://doi.org/10.1039/C39890001826

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abstract = "Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.",

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AU - Frolow, Felix

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N2 - Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

AB - Si-Cl bonds undergo facile, rarely observed oxidative addition to (C 8H14)Ir(PMe3)3Cl (1) to yield, when MeSiCl3 is used, the crystallographically characterized mer-Ir(PMe3)3(Cl)2(SiMeCl2), exhibiting a short Ir-Si bond; reaction of (1) and of other electron-rich IrI complexes with Me3SiCl yields Ir-H complexes, probably arising from a rare silyl β-hydride elimination process.

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Access to Document

10.1039/C39890001826