Oxidative coupling of porphyrins using copper(ii) salts

Bradley J. Brennan, Michael J. Kenney, Paul A. Liddell, Brian R. Cherry, Jian Li, Ana L. Moore, Thomas A. Moore, Devens Gust

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

A method for radical coupling of porphyrins using copper(ii) salts as one-electron oxidants was developed. A Zn(ii)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

Original languageEnglish
Pages (from-to)10034-10036
Number of pages3
JournalChemical Communications
Volume47
Issue number36
DOIs
Publication statusPublished - Sep 28 2011

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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