Oxidative coupling of porphyrins using copper(ii) salts

Bradley J. Brennan, Michael J. Kenney, Paul A. Liddell, Brian R. Cherry, Jian Li, Ana L Moore, Thomas A Moore, John Devens Gust

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A method for radical coupling of porphyrins using copper(ii) salts as one-electron oxidants was developed. A Zn(ii)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

Original languageEnglish
Pages (from-to)10034-10036
Number of pages3
JournalChemical Communications
Volume47
Issue number36
DOIs
Publication statusPublished - Sep 28 2011

Fingerprint

Porphyrins
Copper
Salts
Dimers
Bearings (structural)
Oxidants
Oligomers
Electrons

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Brennan, B. J., Kenney, M. J., Liddell, P. A., Cherry, B. R., Li, J., Moore, A. L., ... Gust, J. D. (2011). Oxidative coupling of porphyrins using copper(ii) salts. Chemical Communications, 47(36), 10034-10036. https://doi.org/10.1039/c1cc13596a

Oxidative coupling of porphyrins using copper(ii) salts. / Brennan, Bradley J.; Kenney, Michael J.; Liddell, Paul A.; Cherry, Brian R.; Li, Jian; Moore, Ana L; Moore, Thomas A; Gust, John Devens.

In: Chemical Communications, Vol. 47, No. 36, 28.09.2011, p. 10034-10036.

Research output: Contribution to journalArticle

Brennan, BJ, Kenney, MJ, Liddell, PA, Cherry, BR, Li, J, Moore, AL, Moore, TA & Gust, JD 2011, 'Oxidative coupling of porphyrins using copper(ii) salts', Chemical Communications, vol. 47, no. 36, pp. 10034-10036. https://doi.org/10.1039/c1cc13596a
Brennan BJ, Kenney MJ, Liddell PA, Cherry BR, Li J, Moore AL et al. Oxidative coupling of porphyrins using copper(ii) salts. Chemical Communications. 2011 Sep 28;47(36):10034-10036. https://doi.org/10.1039/c1cc13596a
Brennan, Bradley J. ; Kenney, Michael J. ; Liddell, Paul A. ; Cherry, Brian R. ; Li, Jian ; Moore, Ana L ; Moore, Thomas A ; Gust, John Devens. / Oxidative coupling of porphyrins using copper(ii) salts. In: Chemical Communications. 2011 ; Vol. 47, No. 36. pp. 10034-10036.
@article{2197bab8faeb407f988232c6ae43fe23,
title = "Oxidative coupling of porphyrins using copper(ii) salts",
abstract = "A method for radical coupling of porphyrins using copper(ii) salts as one-electron oxidants was developed. A Zn(ii)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.",
author = "Brennan, {Bradley J.} and Kenney, {Michael J.} and Liddell, {Paul A.} and Cherry, {Brian R.} and Jian Li and Moore, {Ana L} and Moore, {Thomas A} and Gust, {John Devens}",
year = "2011",
month = "9",
day = "28",
doi = "10.1039/c1cc13596a",
language = "English",
volume = "47",
pages = "10034--10036",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "36",

}

TY - JOUR

T1 - Oxidative coupling of porphyrins using copper(ii) salts

AU - Brennan, Bradley J.

AU - Kenney, Michael J.

AU - Liddell, Paul A.

AU - Cherry, Brian R.

AU - Li, Jian

AU - Moore, Ana L

AU - Moore, Thomas A

AU - Gust, John Devens

PY - 2011/9/28

Y1 - 2011/9/28

N2 - A method for radical coupling of porphyrins using copper(ii) salts as one-electron oxidants was developed. A Zn(ii)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

AB - A method for radical coupling of porphyrins using copper(ii) salts as one-electron oxidants was developed. A Zn(ii)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

UR - http://www.scopus.com/inward/record.url?scp=80052317701&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80052317701&partnerID=8YFLogxK

U2 - 10.1039/c1cc13596a

DO - 10.1039/c1cc13596a

M3 - Article

VL - 47

SP - 10034

EP - 10036

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 36

ER -