Oxidatively induced reductive elimination. A novel titanium complex resulting from C-F bond activation

Mark J. Burk, Donna L. Staley, William Tumas

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

Reaction between bis(cyclopentadienyl)titanacyclobutanes (1) and tetrakis(trifluoromethyl)cyclopentadienone (2) results in formal reductive elimination of cyclopropanes and activation of an sp3 C-F bond in (2) to afford the novel organometallic product (3) (structurally characterized by X-ray crystallography).

Original languageEnglish
Pages (from-to)809-810
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - 1990

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Cyclopropanes
X ray crystallography
X Ray Crystallography
Organometallics
Titanium
Chemical activation

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Oxidatively induced reductive elimination. A novel titanium complex resulting from C-F bond activation. / Burk, Mark J.; Staley, Donna L.; Tumas, William.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 1990, p. 809-810.

Research output: Contribution to journalArticle

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