Oxidatively induced reductive elimination. A novel titanium complex resulting from C-F bond activation

Mark J. Burk, Donna L. Staley, William Tumas

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Abstract

Reaction between bis(cyclopentadienyl)titanacyclobutanes (1) and tetrakis(trifluoromethyl)cyclopentadienone (2) results in formal reductive elimination of cyclopropanes and activation of an sp3 C-F bond in (2) to afford the novel organometallic product (3) (structurally characterized by X-ray crystallography).

Original languageEnglish
Pages (from-to)809-810
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number11
DOIs
Publication statusPublished - 1990

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ASJC Scopus subject areas

  • Molecular Medicine

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