Abstract
Abstraction of chloride from the Pd complex {[η3-2,6-(tBu2PCH2) 2C6H3)]PdCl with AgBF4 in THF gives {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(THF)}+BF4 -. Attemped crystallization of this THF complex produced the aqua complex {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -. Crystal structures of two crystalline forms of this compound are reported. In {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -·THF, one hydrogen of the water is hydrogen bonded to the oxygen of the THF, and the other hydrogen is hydrogen bonded to an F of the BF4 - anion. Another crystalline form has no THF, but has both of the hydrogens of water hydrogen bonded to different BF4 - anions, such that two different BF4 - anions bridge two {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+ cations. A crystal structure is also reported for the palladium chloride complex [η3-2,6-(tBu2PCH2) 2C6H3)]PdCl.
| Original language | English |
|---|---|
| Pages (from-to) | 52-58 |
| Number of pages | 7 |
| Journal | Inorganica Chimica Acta |
| Volume | 330 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Mar 13 2002 |
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Keywords
- Aqua complexes
- Crystal structures
- Hydrogen bonding
- Palladium complexes
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Palladium complexes with PCP ligands. - Preparation and structural studies of two forms of [(PCP)Pd(OH2)]+BF4 - . / Kimmich, Barbara F M; Marshall, William J.; Fagan, Paul J.; Hauptman, Elisabeth; Bullock, R Morris.
In: Inorganica Chimica Acta, Vol. 330, No. 1, 13.03.2002, p. 52-58.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Palladium complexes with PCP ligands. - Preparation and structural studies of two forms of [(PCP)Pd(OH2)]+BF4 -
AU - Kimmich, Barbara F M
AU - Marshall, William J.
AU - Fagan, Paul J.
AU - Hauptman, Elisabeth
AU - Bullock, R Morris
PY - 2002/3/13
Y1 - 2002/3/13
N2 - Abstraction of chloride from the Pd complex {[η3-2,6-(tBu2PCH2) 2C6H3)]PdCl with AgBF4 in THF gives {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(THF)}+BF4 -. Attemped crystallization of this THF complex produced the aqua complex {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -. Crystal structures of two crystalline forms of this compound are reported. In {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -·THF, one hydrogen of the water is hydrogen bonded to the oxygen of the THF, and the other hydrogen is hydrogen bonded to an F of the BF4 - anion. Another crystalline form has no THF, but has both of the hydrogens of water hydrogen bonded to different BF4 - anions, such that two different BF4 - anions bridge two {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+ cations. A crystal structure is also reported for the palladium chloride complex [η3-2,6-(tBu2PCH2) 2C6H3)]PdCl.
AB - Abstraction of chloride from the Pd complex {[η3-2,6-(tBu2PCH2) 2C6H3)]PdCl with AgBF4 in THF gives {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(THF)}+BF4 -. Attemped crystallization of this THF complex produced the aqua complex {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -. Crystal structures of two crystalline forms of this compound are reported. In {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+BF 4 -·THF, one hydrogen of the water is hydrogen bonded to the oxygen of the THF, and the other hydrogen is hydrogen bonded to an F of the BF4 - anion. Another crystalline form has no THF, but has both of the hydrogens of water hydrogen bonded to different BF4 - anions, such that two different BF4 - anions bridge two {[η3-2,6-(tBu2PCH2) 2C6H3)]Pd(OH2)}+ cations. A crystal structure is also reported for the palladium chloride complex [η3-2,6-(tBu2PCH2) 2C6H3)]PdCl.
KW - Aqua complexes
KW - Crystal structures
KW - Hydrogen bonding
KW - Palladium complexes
UR - http://www.scopus.com/inward/record.url?scp=0037070419&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037070419&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(01)00736-8
DO - 10.1016/S0020-1693(01)00736-8
M3 - Article
VL - 330
SP - 52
EP - 58
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1
ER -