PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere

Jianbing Zhang, Jianbo Gao, Carena P. Church, Elisa M. Miller, Joseph M. Luther, Victor I Klimov, Matthew C. Beard

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

Colloidal quantum dots (QDs) are promising candidates for the next generation of photovoltaic (PV) technologies. Much of the progress in QD PVs is based on using PbS QDs, partly because they are stable under ambient conditions. There is considerable interest in extending this work to PbSe QDs, which have shown an enhanced photocurrent due to multiple exciton generation (MEG). One problem complicating such device-based studies is a poor stability of PbSe QDs toward exposure to ambient air. Here we develop a direct cation exchange synthesis to produce PbSe QDs with a large range of sizes and with in situ chloride and cadmium passivation. The synthesized QDs have excellent air stability, maintaining their photoluminescence quantum yield under ambient conditions for more than 30 days. Using these QDs, we fabricate high-performance solar cells without any protection and demonstrate a power conversion efficiency exceeding 6%, which is a current record for PbSe QD solar cells.

Original languageEnglish
Pages (from-to)6010-6015
Number of pages6
JournalNano Letters
Volume14
Issue number10
DOIs
Publication statusPublished - Oct 8 2014

Fingerprint

Semiconductor quantum dots
Solar cells
solar cells
quantum dots
atmospheres
lead selenide
Cadmium Chloride
air
Quantum yield
Air
Photocurrents
Passivation
Excitons
Cadmium
cadmium
passivity
Conversion efficiency
photocurrents
Cations
Ion exchange

Keywords

  • Cation exchange
  • PbSe
  • Quantum Dots
  • Solar Energy Conversion
  • Stability

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanical Engineering

Cite this

Zhang, J., Gao, J., Church, C. P., Miller, E. M., Luther, J. M., Klimov, V. I., & Beard, M. C. (2014). PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere. Nano Letters, 14(10), 6010-6015. https://doi.org/10.1021/nl503085v

PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere. / Zhang, Jianbing; Gao, Jianbo; Church, Carena P.; Miller, Elisa M.; Luther, Joseph M.; Klimov, Victor I; Beard, Matthew C.

In: Nano Letters, Vol. 14, No. 10, 08.10.2014, p. 6010-6015.

Research output: Contribution to journalArticle

Zhang, J, Gao, J, Church, CP, Miller, EM, Luther, JM, Klimov, VI & Beard, MC 2014, 'PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere', Nano Letters, vol. 14, no. 10, pp. 6010-6015. https://doi.org/10.1021/nl503085v
Zhang, Jianbing ; Gao, Jianbo ; Church, Carena P. ; Miller, Elisa M. ; Luther, Joseph M. ; Klimov, Victor I ; Beard, Matthew C. / PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere. In: Nano Letters. 2014 ; Vol. 14, No. 10. pp. 6010-6015.
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