Abstract
Phase composition and compatibilities at 930° to 950°C were determined for the system Eu2O3-BaO-CuO in air. The binary compound Eu2CuO4 dissolves Ba to the extent 0 ≤ x ≤ 0.02 in Eu2-xBaxCuO4, whereas the other binary compounds, Eu2BaO4 and BaCuO2, do not exhibit solid solubility. Three ternary compounds were obtained, Eu2BaCuO5 and two solid solution phases. The first contains the 90 K '123' superconductor and has solubility limits represented by Eu1+xBa2-xCu3O7±y, where 0 ≤ x ≤ 0.5. The second has a solubility limit represented as Eu1+xBa8-xCu4Oy, where 0 ≤ x ≤ 0.44. The limited solid solution range of this phase provides insight concerning the probable solid solution range of the analogous phase in the Y2O3-BaO-CuO system.
| Original language | English |
|---|---|
| Pages (from-to) | 3088-3090 |
| Number of pages | 3 |
| Journal | Journal of the American Ceramic Society |
| Volume | 73 |
| Issue number | 10 |
| Publication status | Published - Oct 1990 |
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ASJC Scopus subject areas
- Ceramics and Composites
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Phase composition and compatibilities at 930°C to 950°C in the system europium (III) oxide-barium oxide-copper(II) oxide in air. / Pieczulewski, C. N.; McAdams, J. E.; Mason, Thomas O.
In: Journal of the American Ceramic Society, Vol. 73, No. 10, 10.1990, p. 3088-3090.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Phase composition and compatibilities at 930°C to 950°C in the system europium (III) oxide-barium oxide-copper(II) oxide in air
AU - Pieczulewski, C. N.
AU - McAdams, J. E.
AU - Mason, Thomas O
PY - 1990/10
Y1 - 1990/10
N2 - Phase composition and compatibilities at 930° to 950°C were determined for the system Eu2O3-BaO-CuO in air. The binary compound Eu2CuO4 dissolves Ba to the extent 0 ≤ x ≤ 0.02 in Eu2-xBaxCuO4, whereas the other binary compounds, Eu2BaO4 and BaCuO2, do not exhibit solid solubility. Three ternary compounds were obtained, Eu2BaCuO5 and two solid solution phases. The first contains the 90 K '123' superconductor and has solubility limits represented by Eu1+xBa2-xCu3O7±y, where 0 ≤ x ≤ 0.5. The second has a solubility limit represented as Eu1+xBa8-xCu4Oy, where 0 ≤ x ≤ 0.44. The limited solid solution range of this phase provides insight concerning the probable solid solution range of the analogous phase in the Y2O3-BaO-CuO system.
AB - Phase composition and compatibilities at 930° to 950°C were determined for the system Eu2O3-BaO-CuO in air. The binary compound Eu2CuO4 dissolves Ba to the extent 0 ≤ x ≤ 0.02 in Eu2-xBaxCuO4, whereas the other binary compounds, Eu2BaO4 and BaCuO2, do not exhibit solid solubility. Three ternary compounds were obtained, Eu2BaCuO5 and two solid solution phases. The first contains the 90 K '123' superconductor and has solubility limits represented by Eu1+xBa2-xCu3O7±y, where 0 ≤ x ≤ 0.5. The second has a solubility limit represented as Eu1+xBa8-xCu4Oy, where 0 ≤ x ≤ 0.44. The limited solid solution range of this phase provides insight concerning the probable solid solution range of the analogous phase in the Y2O3-BaO-CuO system.
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M3 - Article
AN - SCOPUS:0025505761
VL - 73
SP - 3088
EP - 3090
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
SN - 0002-7820
IS - 10
ER -