Abstract
The phase relationships in the pseudobinary MgMoO4-Mg3V2O8 system have been determined by differential thermal analysis and X-ray diffraction analysis. The intermediate compound Mg2.5VMoO8 was found to exhibit a considerable solid solution Mg2.5+xV1+2xMo1-2xO8 (-0.05 ≤ * ≤ 0.05) at 1100 °C in air. Single crystals with composition of Mg2.54V1.08Mo0.92O8 were successfully grown from the Mg-V-Mo-Oxide flux. Mg2.54V1.08Mo0.92O8 crystallizes in the orthorhombic system, space group Pnma with a = 5.058(1) Å, b = 10.307(3) Å, c = 17.402(4) Å, Z = 6. The vanadium and molybdenum cations remain in their highest oxidation states and charge neutrality associated with the variation of the V/Mo atomic ratio is balanced by an increase or decrease in the number of magnesium cations in the crystal.
| Original language | English |
|---|---|
| Pages (from-to) | 51-58 |
| Number of pages | 8 |
| Journal | Journal of Alloys and Compounds |
| Volume | 243 |
| Issue number | 1-2 |
| Publication status | Published - Oct 15 1996 |
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Keywords
- Crystal structure
- MgVMoO and MgMoO-MgVO system
- Phase diagram
ASJC Scopus subject areas
- Metals and Alloys
Cite this
Phase relations in the MgMoO4-Mg3V2O8 system and crystal structure of Mg2.54V1.08Mo0.92O8 1. / Wang, Xiandong; Stern, Charlotte L.; Poeppelmeier, Kenneth R.
In: Journal of Alloys and Compounds, Vol. 243, No. 1-2, 15.10.1996, p. 51-58.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Phase relations in the MgMoO4-Mg3V2O8 system and crystal structure of Mg2.54V1.08Mo0.92O8 1
AU - Wang, Xiandong
AU - Stern, Charlotte L.
AU - Poeppelmeier, Kenneth R
PY - 1996/10/15
Y1 - 1996/10/15
N2 - The phase relationships in the pseudobinary MgMoO4-Mg3V2O8 system have been determined by differential thermal analysis and X-ray diffraction analysis. The intermediate compound Mg2.5VMoO8 was found to exhibit a considerable solid solution Mg2.5+xV1+2xMo1-2xO8 (-0.05 ≤ * ≤ 0.05) at 1100 °C in air. Single crystals with composition of Mg2.54V1.08Mo0.92O8 were successfully grown from the Mg-V-Mo-Oxide flux. Mg2.54V1.08Mo0.92O8 crystallizes in the orthorhombic system, space group Pnma with a = 5.058(1) Å, b = 10.307(3) Å, c = 17.402(4) Å, Z = 6. The vanadium and molybdenum cations remain in their highest oxidation states and charge neutrality associated with the variation of the V/Mo atomic ratio is balanced by an increase or decrease in the number of magnesium cations in the crystal.
AB - The phase relationships in the pseudobinary MgMoO4-Mg3V2O8 system have been determined by differential thermal analysis and X-ray diffraction analysis. The intermediate compound Mg2.5VMoO8 was found to exhibit a considerable solid solution Mg2.5+xV1+2xMo1-2xO8 (-0.05 ≤ * ≤ 0.05) at 1100 °C in air. Single crystals with composition of Mg2.54V1.08Mo0.92O8 were successfully grown from the Mg-V-Mo-Oxide flux. Mg2.54V1.08Mo0.92O8 crystallizes in the orthorhombic system, space group Pnma with a = 5.058(1) Å, b = 10.307(3) Å, c = 17.402(4) Å, Z = 6. The vanadium and molybdenum cations remain in their highest oxidation states and charge neutrality associated with the variation of the V/Mo atomic ratio is balanced by an increase or decrease in the number of magnesium cations in the crystal.
KW - Crystal structure
KW - MgVMoO and MgMoO-MgVO system
KW - Phase diagram
UR - http://www.scopus.com/inward/record.url?scp=0041374841&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0041374841&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0041374841
VL - 243
SP - 51
EP - 58
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
IS - 1-2
ER -