Phenanthrene-bridged diarylethenes: Synthesis, photochromism and non-destructive readout

Junjie He; Tingting Wang; Shuxin Chen; Ruiping Zheng; Huiyuan Chen; Jing Li; Heping Zeng

doi:10.1016/j.jphotochem.2013.11.016

Phenanthrene-bridged diarylethenes: Synthesis, photochromism and non-destructive readout

Junjie He, Tingting Wang, Shuxin Chen, Ruiping Zheng, Huiyuan Chen, Jing Li, Heping Zeng

Rutgers University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Here we report on the synthesis and photochromism of a group of newly designed phenanthrene-bridged diarylethenes. The structure of one diarylethene derivative was determined by single crystal X-ray diffraction analysis. The photochromic dyes cyclize smoothly in polar organic solvents and water upon UV light irradiation while undergo fading under visible light. These photochromic materials have non-destructive readout capability through fluorescent modulation. Fluorescent read-out lights of them are 390 and 385 nm respectively. The non-destructive read out capability of them was studied with density functional theory and the results indicated that the cyclization probably took place at the second rather than the first excited states.

Original language	English
Pages (from-to)	45-52
Number of pages	8
Journal	Journal of Photochemistry and Photobiology A: Chemistry
Volume	277
DOIs	https://doi.org/10.1016/j.jphotochem.2013.11.016
Publication status	Published - Mar 1 2014

Keywords

Diarylethene
Non-destructive readout
Phenanthrene
Photochromism
Solvent effect

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Physics and Astronomy(all)

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title = "Phenanthrene-bridged diarylethenes: Synthesis, photochromism and non-destructive readout",

abstract = "Here we report on the synthesis and photochromism of a group of newly designed phenanthrene-bridged diarylethenes. The structure of one diarylethene derivative was determined by single crystal X-ray diffraction analysis. The photochromic dyes cyclize smoothly in polar organic solvents and water upon UV light irradiation while undergo fading under visible light. These photochromic materials have non-destructive readout capability through fluorescent modulation. Fluorescent read-out lights of them are 390 and 385 nm respectively. The non-destructive read out capability of them was studied with density functional theory and the results indicated that the cyclization probably took place at the second rather than the first excited states.",

keywords = "Diarylethene, Non-destructive readout, Phenanthrene, Photochromism, Solvent effect",

author = "Junjie He and Tingting Wang and Shuxin Chen and Ruiping Zheng and Huiyuan Chen and Jing Li and Heping Zeng",

note = "Funding Information: The authors acknowledge financial support from the National Natural Science Foundation of China (No. 21071054 ) and Project of Guangdong Province of Science and Technology of China ( 2009B091300045, 2008B010800030, 2010B090400495 ). Prof. Jing Li is a Cheung Kong Scholar associated with SCUT. ",

year = "2014",

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doi = "10.1016/j.jphotochem.2013.11.016",

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journal = "Journal of Photochemistry and Photobiology A: Chemistry",

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T1 - Phenanthrene-bridged diarylethenes

T2 - Synthesis, photochromism and non-destructive readout

AU - He, Junjie

AU - Wang, Tingting

AU - Chen, Shuxin

AU - Zheng, Ruiping

AU - Chen, Huiyuan

AU - Li, Jing

AU - Zeng, Heping

N1 - Funding Information: The authors acknowledge financial support from the National Natural Science Foundation of China (No. 21071054 ) and Project of Guangdong Province of Science and Technology of China ( 2009B091300045, 2008B010800030, 2010B090400495 ). Prof. Jing Li is a Cheung Kong Scholar associated with SCUT.

PY - 2014/3/1

Y1 - 2014/3/1

N2 - Here we report on the synthesis and photochromism of a group of newly designed phenanthrene-bridged diarylethenes. The structure of one diarylethene derivative was determined by single crystal X-ray diffraction analysis. The photochromic dyes cyclize smoothly in polar organic solvents and water upon UV light irradiation while undergo fading under visible light. These photochromic materials have non-destructive readout capability through fluorescent modulation. Fluorescent read-out lights of them are 390 and 385 nm respectively. The non-destructive read out capability of them was studied with density functional theory and the results indicated that the cyclization probably took place at the second rather than the first excited states.

AB - Here we report on the synthesis and photochromism of a group of newly designed phenanthrene-bridged diarylethenes. The structure of one diarylethene derivative was determined by single crystal X-ray diffraction analysis. The photochromic dyes cyclize smoothly in polar organic solvents and water upon UV light irradiation while undergo fading under visible light. These photochromic materials have non-destructive readout capability through fluorescent modulation. Fluorescent read-out lights of them are 390 and 385 nm respectively. The non-destructive read out capability of them was studied with density functional theory and the results indicated that the cyclization probably took place at the second rather than the first excited states.

KW - Diarylethene

KW - Non-destructive readout

KW - Phenanthrene

KW - Photochromism

KW - Solvent effect

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U2 - 10.1016/j.jphotochem.2013.11.016

DO - 10.1016/j.jphotochem.2013.11.016

M3 - Article

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VL - 277

SP - 45

EP - 52

JO - Journal of Photochemistry and Photobiology A: Chemistry

JF - Journal of Photochemistry and Photobiology A: Chemistry

SN - 1010-6030

ER -

Phenanthrene-bridged diarylethenes: Synthesis, photochromism and non-destructive readout

Abstract

Keywords

ASJC Scopus subject areas

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