Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic

Anindya Roy; Christopher Madden; Giovanna Ghirlanda

doi:10.1039/c2cc34470j

Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic

Anindya Roy, Christopher Madden, Giovanna Ghirlanda

Arizona State University

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we present a bioinspired mimic designed by anchoring a diiron hexacarbonyl cluster to a model helical peptide via an artificial dithiol amino acid. The [FeFe]–peptide complex catalyses photo-induced production of hydrogen in water.

Original language	English
Pages (from-to)	9816-9818
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	79
DOIs	https://doi.org/10.1039/c2cc34470j
Publication status	Published - Sep 10 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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