Abstract
There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we present a bioinspired mimic designed by anchoring a diiron hexacarbonyl cluster to a model helical peptide via an artificial dithiol amino acid. The [FeFe]-peptide complex catalyses photo-induced production of hydrogen in water.
| Original language | English |
|---|---|
| Pages (from-to) | 9816-9818 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 48 |
| Issue number | 79 |
| DOIs | |
| Publication status | Published - Oct 11 2012 |
Fingerprint
ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic. / Roy, Anindya; Madden, Christopher; Ghirlanda, Giovanna.
In: Chemical Communications, Vol. 48, No. 79, 11.10.2012, p. 9816-9818.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Photo-induced hydrogen production in a helical peptide incorporating a [FeFe] hydrogenase active site mimic
AU - Roy, Anindya
AU - Madden, Christopher
AU - Ghirlanda, Giovanna
PY - 2012/10/11
Y1 - 2012/10/11
N2 - There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we present a bioinspired mimic designed by anchoring a diiron hexacarbonyl cluster to a model helical peptide via an artificial dithiol amino acid. The [FeFe]-peptide complex catalyses photo-induced production of hydrogen in water.
AB - There is growing interest in the development of hydrogenase mimics for solar fuel production. Here, we present a bioinspired mimic designed by anchoring a diiron hexacarbonyl cluster to a model helical peptide via an artificial dithiol amino acid. The [FeFe]-peptide complex catalyses photo-induced production of hydrogen in water.
UR - http://www.scopus.com/inward/record.url?scp=84866245294&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84866245294&partnerID=8YFLogxK
U2 - 10.1039/c2cc34470j
DO - 10.1039/c2cc34470j
M3 - Article
C2 - 22895256
AN - SCOPUS:84866245294
VL - 48
SP - 9816
EP - 9818
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 79
ER -