Photo-, thermally, and pH-responsive microgels

Antonio Garcia, Manuel Marquez, Tong Cai, Rohit Rosario, Zhibing Hu, John Devens Gust, Mark Hayes, Scan A. Vail, Choong Do Park

Research output: Contribution to journalArticle

165 Citations (Scopus)

Abstract

Microgels with photo-, thermally, and pH-responsive properties in aqueous suspension have been synthesized and characterized using dynamic light scattering and UV- visible spectroscopy. The new route involved first preparing poly(N-isopropylacrylamide) (PNIPAM)-allylamine copolymer microgels and a spiropyran photochrome (SP) bearing a carboxylic acid group. Then the functionalized spiropyran was coupled to the microgel via an amide bond. The dark-equilibrated gel particles feature spiropyran molecules in the polar, merocyanine form. After irradiation of visible light, the particle size becomes smaller because spiropyran changes to the relatively nonpolar, closed spiro form. The PNIPAM-SP microgels undergo a volume phase transition in water from a swollen state to a collapsed state with increasing temperature under all light conditions. However, the transition temperature range of the PNIPAM-SP is much broader than that for the PNIPAM without SP. The PNIPAM-SP microgels are monodisperse and self-assemble into a crystalline lattice while in suspension. The UV-visible spectra of an aqueous suspension of PNIPAM-SP microgel in the dark-adapted, merocyanine form showed both an absorption peak around 512 nm due to the merocyanine (giving a reddish color to the suspension) and two sharp peaks from Bragg diffraction of colloidal crystallites. Upon visible irradiation, the 512-nm band bleached significantly due to spiropyran photoisomerization. The spiropyran photoisomerization and accompanying color changes of the suspension were reversible upon alternating dark, UV, and visible light irradiation. Due to the residues of ainine groups, the swelling capability of PNIPAM-SP microgels reduces as the pH value is changed from 7 to 10.

Original languageEnglish
Pages (from-to)224-229
Number of pages6
JournalLangmuir
Volume23
Issue number1
DOIs
Publication statusPublished - Jan 2 2007

Fingerprint

Photoisomerization
Irradiation
Bearings (structural)
Color
irradiation
Dynamic light scattering
Suspensions
Carboxylic acids
Crystallites
Amides
Crystal lattices
Particles (particulate matter)
Superconducting transition temperature
Swelling
color
Gels
Copolymers
Diffraction
Phase transitions
Particle size

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

Cite this

Garcia, A., Marquez, M., Cai, T., Rosario, R., Hu, Z., Gust, J. D., ... Park, C. D. (2007). Photo-, thermally, and pH-responsive microgels. Langmuir, 23(1), 224-229. https://doi.org/10.1021/la061632n

Photo-, thermally, and pH-responsive microgels. / Garcia, Antonio; Marquez, Manuel; Cai, Tong; Rosario, Rohit; Hu, Zhibing; Gust, John Devens; Hayes, Mark; Vail, Scan A.; Park, Choong Do.

In: Langmuir, Vol. 23, No. 1, 02.01.2007, p. 224-229.

Research output: Contribution to journalArticle

Garcia, A, Marquez, M, Cai, T, Rosario, R, Hu, Z, Gust, JD, Hayes, M, Vail, SA & Park, CD 2007, 'Photo-, thermally, and pH-responsive microgels', Langmuir, vol. 23, no. 1, pp. 224-229. https://doi.org/10.1021/la061632n
Garcia A, Marquez M, Cai T, Rosario R, Hu Z, Gust JD et al. Photo-, thermally, and pH-responsive microgels. Langmuir. 2007 Jan 2;23(1):224-229. https://doi.org/10.1021/la061632n
Garcia, Antonio ; Marquez, Manuel ; Cai, Tong ; Rosario, Rohit ; Hu, Zhibing ; Gust, John Devens ; Hayes, Mark ; Vail, Scan A. ; Park, Choong Do. / Photo-, thermally, and pH-responsive microgels. In: Langmuir. 2007 ; Vol. 23, No. 1. pp. 224-229.
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