Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

Dmitry Polyansky; Diane Cabelli; James T. Muckerman; Etsuko Fujita; Take Aki Koizumi; Takashi Fukushima; Tohru Wada; Koji Tanaka

doi:10.1002/anie.200700304

Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand

Dmitry Polyansky, Diane Cabelli, James T. Muckerman, Etsuko Fujita, Take Aki Koizumi, Takashi Fukushima, Tohru Wada, Koji Tanaka

Brookhaven National Laboratory

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD ⁺/NADH (NAD⁺ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)₂(pbn)]²⁺ ([1]²⁺; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]²⁺ and triethylamine are irradiated with visible light, [(1)HH]²⁺ is produced cleanly (see scheme).

Original language	English
Pages (from-to)	4169-4172
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	22
DOIs	https://doi.org/10.1002/anie.200700304
Publication status	Published - Jun 27 2007

Keywords

Charge transfer
Hydrides
NADH
Photochemistry
Ruthenium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand. / Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T.; Fujita, Etsuko; Koizumi, Take Aki; Fukushima, Takashi; Wada, Tohru; Tanaka, Koji.

In: Angewandte Chemie - International Edition, Vol. 46, No. 22, 27.06.2007, p. 4169-4172.

Research output: Contribution to journal › Article › peer-review

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abstract = "(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).",

keywords = "Charge transfer, Hydrides, NADH, Photochemistry, Ruthenium",

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AU - Polyansky, Dmitry

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AU - Fujita, Etsuko

AU - Koizumi, Take Aki

AU - Fukushima, Takashi

AU - Wada, Tohru

AU - Tanaka, Koji

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