Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

Dmitry Polyansky; Diane Cabelli; James T. Muckerman; Etsuko Fujita; Take Aki Koizumi; Takashi Fukushima; Tohru Wada; Koji Tanaka

doi:10.1002/anie.200700304

Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand

Dmitry Polyansky, Diane Cabelli, James T. Muckerman, Etsuko Fujita, Take Aki Koizumi, Takashi Fukushima, Tohru Wada, Koji Tanaka

Brookhaven National Laboratory

Research output: Contribution to journal › Article

69 Citations (Scopus)

Abstract

(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD ⁺/NADH (NAD⁺ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)₂(pbn)]²⁺ ([1]²⁺; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]²⁺ and triethylamine are irradiated with visible light, [(1)HH]²⁺ is produced cleanly (see scheme).

Original language	English
Pages (from-to)	4169-4172
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	22
DOIs	https://doi.org/10.1002/anie.200700304
Publication status	Published - Jun 27 2007

Keywords

Charge transfer
Hydrides
NADH
Photochemistry
Ruthenium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200700304

Fingerprint Dive into the research topics of 'Photochemical and radiolytic production of an organic hydride donor with a Ru<sup>II</sup> complex containing an NAD<sup>+</sup> model ligand'. Together they form a unique fingerprint.

Cite this

Polyansky, D., Cabelli, D., Muckerman, J. T., Fujita, E., Koizumi, T. A., Fukushima, T., Wada, T., & Tanaka, K. (2007). Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand. Angewandte Chemie - International Edition, 46(22), 4169-4172. https://doi.org/10.1002/anie.200700304

Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand. / Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T.; Fujita, Etsuko; Koizumi, Take Aki; Fukushima, Takashi; Wada, Tohru; Tanaka, Koji.

In: Angewandte Chemie - International Edition, Vol. 46, No. 22, 27.06.2007, p. 4169-4172.

Research output: Contribution to journal › Article

@article{97f5d5a95e1a48069d0d1888bffdadca,

title = "Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand",

abstract = "(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).",

keywords = "Charge transfer, Hydrides, NADH, Photochemistry, Ruthenium",

author = "Dmitry Polyansky and Diane Cabelli and Muckerman, {James T.} and Etsuko Fujita and Koizumi, {Take Aki} and Takashi Fukushima and Tohru Wada and Koji Tanaka",

year = "2007",

month = jun,

day = "27",

doi = "10.1002/anie.200700304",

language = "English",

volume = "46",

pages = "4169--4172",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "22",

}

TY - JOUR

T1 - Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

AU - Polyansky, Dmitry

AU - Cabelli, Diane

AU - Muckerman, James T.

AU - Fujita, Etsuko

AU - Koizumi, Take Aki

AU - Fukushima, Takashi

AU - Wada, Tohru

AU - Tanaka, Koji

PY - 2007/6/27

Y1 - 2007/6/27

N2 - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

AB - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

KW - Charge transfer

KW - Hydrides

KW - NADH

KW - Photochemistry

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=34250720497&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250720497&partnerID=8YFLogxK

U2 - 10.1002/anie.200700304

DO - 10.1002/anie.200700304

M3 - Article

C2 - 17450514

AN - SCOPUS:34250720497

VL - 46

SP - 4169

EP - 4172

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 22

ER -