Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

Dmitry Polyansky; Diane Cabelli; James T. Muckerman; Etsuko Fujita; Take Aki Koizumi; Takashi Fukushima; Tohru Wada; Koji Tanaka

doi:10.1002/anie.200700304

Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand

Dmitry Polyansky, Diane Cabelli, James T. Muckerman, Etsuko Fujita, Take Aki Koizumi, Takashi Fukushima, Tohru Wada, Koji Tanaka

Brookhaven National Laboratory

Research output: Contribution to journal › Article

69 Citations (Scopus)

Abstract

(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD ⁺/NADH (NAD⁺ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)₂(pbn)]²⁺ ([1]²⁺; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]²⁺ and triethylamine are irradiated with visible light, [(1)HH]²⁺ is produced cleanly (see scheme).

Original language	English
Pages (from-to)	4169-4172
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	22
DOIs	https://doi.org/10.1002/anie.200700304
Publication status	Published - Jun 27 2007

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Keywords

Charge transfer
Hydrides
NADH
Photochemistry
Ruthenium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Polyansky, D., Cabelli, D., Muckerman, J. T., Fujita, E., Koizumi, T. A., Fukushima, T., Wada, T., & Tanaka, K. (2007). Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand. Angewandte Chemie - International Edition, 46(22), 4169-4172. https://doi.org/10.1002/anie.200700304

Photochemical and radiolytic production of an organic hydride donor with a Ru^II complex containing an NAD⁺ model ligand. / Polyansky, Dmitry; Cabelli, Diane; Muckerman, James T.; Fujita, Etsuko; Koizumi, Take Aki; Fukushima, Takashi; Wada, Tohru; Tanaka, Koji.

In: Angewandte Chemie - International Edition, Vol. 46, No. 22, 27.06.2007, p. 4169-4172.

Research output: Contribution to journal › Article

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10.1002/anie.200700304