Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

Dmitry Polyansky, Diane Cabelli, James Muckerman, Etsuko Fujita, Take Aki Koizumi, Takashi Fukushima, Tohru Wada, Koji Tanaka

Research output: Contribution to journal › Article

69 Citations (Scopus)

Abstract

(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

Original languageEnglish
Pages (from-to)4169-4172
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number22
DOIs
Publication statusPublished - 2007

Fingerprint

Hydrides
NAD
Ligands
Electrochemical properties

Keywords

  • Charge transfer
  • Hydrides
  • NADH
  • Photochemistry
  • Ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand. / Polyansky, Dmitry; Cabelli, Diane; Muckerman, James; Fujita, Etsuko; Koizumi, Take Aki; Fukushima, Takashi; Wada, Tohru; Tanaka, Koji.

In: Angewandte Chemie - International Edition, Vol. 46, No. 22, 2007, p. 4169-4172.

Research output: Contribution to journal › Article

Polyansky, D, Cabelli, D, Muckerman, J, Fujita, E, Koizumi, TA, Fukushima, T, Wada, T & Tanaka, K 2007, 'Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand', Angewandte Chemie - International Edition, vol. 46, no. 22, pp. 4169-4172. https://doi.org/10.1002/anie.200700304
Polyansky D, Cabelli D, Muckerman J, Fujita E, Koizumi TA, Fukushima T et al. Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand. Angewandte Chemie - International Edition. 2007;46(22):4169-4172. https://doi.org/10.1002/anie.200700304
Polyansky, Dmitry ; Cabelli, Diane ; Muckerman, James ; Fujita, Etsuko ; Koizumi, Take Aki ; Fukushima, Takashi ; Wada, Tohru ; Tanaka, Koji. / Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand. In: Angewandte Chemie - International Edition. 2007 ; Vol. 46, No. 22. pp. 4169-4172.
@article{97f5d5a95e1a48069d0d1888bffdadca,
title = "Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand",
abstract = "(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).",
keywords = "Charge transfer, Hydrides, NADH, Photochemistry, Ruthenium",
author = "Dmitry Polyansky and Diane Cabelli and James Muckerman and Etsuko Fujita and Koizumi, {Take Aki} and Takashi Fukushima and Tohru Wada and Koji Tanaka",
year = "2007",
doi = "10.1002/anie.200700304",
language = "English",
volume = "46",
pages = "4169--4172",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "22",

}

TY - JOUR

T1 - Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

AU - Polyansky, Dmitry

AU - Cabelli, Diane

AU - Muckerman, James

AU - Fujita, Etsuko

AU - Koizumi, Take Aki

AU - Fukushima, Takashi

AU - Wada, Tohru

AU - Tanaka, Koji

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

AB - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

KW - Charge transfer

KW - Hydrides

KW - NADH

KW - Photochemistry

KW - Ruthenium

UR - http://www.scopus.com/inward/record.url?scp=34250720497&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250720497&partnerID=8YFLogxK

U2 - 10.1002/anie.200700304

DO - 10.1002/anie.200700304

M3 - Article

C2 - 17450514

AN - SCOPUS:34250720497

VL - 46

SP - 4169

EP - 4172

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 22

ER -

Access to Document