Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand

Dmitry Polyansky, Diane Cabelli, James T. Muckerman, Etsuko Fujita, Take Aki Koizumi, Takashi Fukushima, Tohru Wada, Koji Tanaka

Research output: Contribution to journalArticlepeer-review

70 Citations (Scopus)

Abstract

(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).

Original languageEnglish
Pages (from-to)4169-4172
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number22
DOIs
Publication statusPublished - Jun 27 2007

Keywords

  • Charge transfer
  • Hydrides
  • NADH
  • Photochemistry
  • Ruthenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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