Abstract
(Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).
Original language | English |
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Pages (from-to) | 4169-4172 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 22 |
DOIs | |
Publication status | Published - 2007 |
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Keywords
- Charge transfer
- Hydrides
- NADH
- Photochemistry
- Ruthenium
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand. / Polyansky, Dmitry; Cabelli, Diane; Muckerman, James; Fujita, Etsuko; Koizumi, Take Aki; Fukushima, Takashi; Wada, Tohru; Tanaka, Koji.
In: Angewandte Chemie - International Edition, Vol. 46, No. 22, 2007, p. 4169-4172.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Photochemical and radiolytic production of an organic hydride donor with a RuII complex containing an NAD+ model ligand
AU - Polyansky, Dmitry
AU - Cabelli, Diane
AU - Muckerman, James
AU - Fujita, Etsuko
AU - Koizumi, Take Aki
AU - Fukushima, Takashi
AU - Wada, Tohru
AU - Tanaka, Koji
PY - 2007
Y1 - 2007
N2 - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).
AB - (Chemical Equation Presented) Role model: The photochemical and electrochemical properties of a polypyridylruthenium complex with an NAD +/NADH (NAD+ = nicotinamide adenine dinucleotide) model ligand, [Ru(bpy)2(pbn)]2+ ([1]2+; bpy = 2,2′-bipyridine, pbn = 2-(2-pyridyl)benzo[b]-1,5-naphthyridine), were investigated. When solutions containing [1]2+ and triethylamine are irradiated with visible light, [(1)HH]2+ is produced cleanly (see scheme).
KW - Charge transfer
KW - Hydrides
KW - NADH
KW - Photochemistry
KW - Ruthenium
UR - http://www.scopus.com/inward/record.url?scp=34250720497&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=34250720497&partnerID=8YFLogxK
U2 - 10.1002/anie.200700304
DO - 10.1002/anie.200700304
M3 - Article
C2 - 17450514
AN - SCOPUS:34250720497
VL - 46
SP - 4169
EP - 4172
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 22
ER -