Photochemical carbon dioxide reduction with metal complexes

Research output: Contribution to journalArticle

202 Citations (Scopus)

Abstract

Transition-metal complexes, CoHMD2+ (HMD = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy)2(CO)Xn+ (bpy = 2,2′-bipyridine, X = CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO2. The thermodynamics and kinetics of CO2 binding to CoHMD+, and spectroscopic characterization of the CO2 adducts of CoHMD+ and [RuI(bpy)(bpy-)(CO)] are described.

Original languageEnglish
Pages (from-to)373-384
Number of pages12
JournalCoordination Chemistry Reviews
Volume185-186
Publication statusPublished - May 1999

Fingerprint

Helmet mounted displays
helmet mounted displays
Coordination Complexes
dienes
Carbon Monoxide
Metal complexes
Carbon Dioxide
adducts
Transition metals
carbon dioxide
Carbon dioxide
electron transfer
transition metals
Thermodynamics
thermodynamics
Kinetics
Electrons
kinetics
metals

Keywords

  • Carbon dioxide reduction
  • Carboxylates
  • Diimine
  • Macrocycles
  • Photocatalysis
  • Small molecule activation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Photochemical carbon dioxide reduction with metal complexes. / Fujita, Etsuko.

In: Coordination Chemistry Reviews, Vol. 185-186, 05.1999, p. 373-384.

Research output: Contribution to journalArticle

@article{426c6e0a93ec458db759fd75b50cd102,
title = "Photochemical carbon dioxide reduction with metal complexes",
abstract = "Transition-metal complexes, CoHMD2+ (HMD = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy)2(CO)Xn+ (bpy = 2,2′-bipyridine, X = CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO2. The thermodynamics and kinetics of CO2 binding to CoHMD+, and spectroscopic characterization of the CO2 adducts of CoHMD+ and [RuI(bpy)(bpy-)(CO)] are described.",
keywords = "Carbon dioxide reduction, Carboxylates, Diimine, Macrocycles, Photocatalysis, Small molecule activation",
author = "Etsuko Fujita",
year = "1999",
month = "5",
language = "English",
volume = "185-186",
pages = "373--384",
journal = "Coordination Chemistry Reviews",
issn = "0010-8545",
publisher = "Elsevier",

}

TY - JOUR

T1 - Photochemical carbon dioxide reduction with metal complexes

AU - Fujita, Etsuko

PY - 1999/5

Y1 - 1999/5

N2 - Transition-metal complexes, CoHMD2+ (HMD = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy)2(CO)Xn+ (bpy = 2,2′-bipyridine, X = CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO2. The thermodynamics and kinetics of CO2 binding to CoHMD+, and spectroscopic characterization of the CO2 adducts of CoHMD+ and [RuI(bpy)(bpy-)(CO)] are described.

AB - Transition-metal complexes, CoHMD2+ (HMD = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) and Ru(bpy)2(CO)Xn+ (bpy = 2,2′-bipyridine, X = CO, Cl, H, etc.), mediate electron transfer in the photochemical reduction of CO2. The thermodynamics and kinetics of CO2 binding to CoHMD+, and spectroscopic characterization of the CO2 adducts of CoHMD+ and [RuI(bpy)(bpy-)(CO)] are described.

KW - Carbon dioxide reduction

KW - Carboxylates

KW - Diimine

KW - Macrocycles

KW - Photocatalysis

KW - Small molecule activation

UR - http://www.scopus.com/inward/record.url?scp=4243270676&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=4243270676&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:4243270676

VL - 185-186

SP - 373

EP - 384

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545

ER -