Abstract
Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.
| Original language | English |
|---|---|
| Pages (from-to) | 2692-2694 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 40 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - Jul 16 2001 |
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Keywords
- Carbonylation
- Photocatalysis
- Photochemistry
- Rhodium
- Supercritical fluids
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Photochemical carbonylation of ethane under snpercritical conditions. / Bitterwolf, Thomas E.; Kline, Dinara Lukmanova; Linehan, John; Yonker, Clement R.; Shane Addleman, R.
In: Angewandte Chemie - International Edition, Vol. 40, No. 14, 16.07.2001, p. 2692-2694.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Photochemical carbonylation of ethane under snpercritical conditions
AU - Bitterwolf, Thomas E.
AU - Kline, Dinara Lukmanova
AU - Linehan, John
AU - Yonker, Clement R.
AU - Shane Addleman, R.
PY - 2001/7/16
Y1 - 2001/7/16
N2 - Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.
AB - Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.
KW - Carbonylation
KW - Photocatalysis
KW - Photochemistry
KW - Rhodium
KW - Supercritical fluids
UR - http://www.scopus.com/inward/record.url?scp=0035898522&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035898522&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P
DO - 10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P
M3 - Article
AN - SCOPUS:0035898522
VL - 40
SP - 2692
EP - 2694
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 14
ER -