Photochemical carbonylation of ethane under snpercritical conditions

Thomas E. Bitterwolf; Dinara Lukmanova Kline; John Linehan; Clement R. Yonker; R. Shane Addleman

doi:10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

Photochemical carbonylation of ethane under snpercritical conditions

Thomas E. Bitterwolf, Dinara Lukmanova Kline, John Linehan, Clement R. Yonker, R. Shane Addleman

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe₃)₂Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe₃ and [Rh(CO)₂(PMe₃)Cl] or [Rh₂(CO)₂-(PMe₃)₂(μ-Cl) ₂] has also been observed.

Original language	English
Pages (from-to)	2692-2694
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	14
DOIs	https://doi.org/10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P
Publication status	Published - Jul 16 2001

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Keywords

Carbonylation
Photocatalysis
Photochemistry
Rhodium
Supercritical fluids

ASJC Scopus subject areas

Chemistry(all)

Cite this

Bitterwolf, T. E., Kline, D. L., Linehan, J., Yonker, C. R., & Shane Addleman, R. (2001). Photochemical carbonylation of ethane under snpercritical conditions. Angewandte Chemie - International Edition, 40(14), 2692-2694. https://doi.org/10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

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abstract = "Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.",

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AB - Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.

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KW - Supercritical fluids

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10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P