Photochemical carbonylation of ethane under snpercritical conditions

Thomas E. Bitterwolf; Dinara Lukmanova Kline; John C. Linehan; Clement R. Yonker; R. Shane Addleman

doi:10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

Photochemical carbonylation of ethane under snpercritical conditions

Thomas E. Bitterwolf, Dinara Lukmanova Kline, John C. Linehan, Clement R. Yonker, R. Shane Addleman

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe₃)₂Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe₃ and [Rh(CO)₂(PMe₃)Cl] or [Rh₂(CO)₂-(PMe₃)₂(μ-Cl) ₂] has also been observed.

Original language	English
Pages (from-to)	2692-2694
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	14
DOIs	https://doi.org/10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P
Publication status	Published - Jul 16 2001

Keywords

Carbonylation
Photocatalysis
Photochemistry
Rhodium
Supercritical fluids

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

Fingerprint Dive into the research topics of 'Photochemical carbonylation of ethane under snpercritical conditions'. Together they form a unique fingerprint.

Cite this

@article{5e539ea55aa94ee6b1741ef539677a3d,

title = "Photochemical carbonylation of ethane under snpercritical conditions",

abstract = "Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.",

keywords = "Carbonylation, Photocatalysis, Photochemistry, Rhodium, Supercritical fluids",

author = "Bitterwolf, {Thomas E.} and Kline, {Dinara Lukmanova} and Linehan, {John C.} and Yonker, {Clement R.} and {Shane Addleman}, R.",

year = "2001",

month = jul,

day = "16",

doi = "10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P",

language = "English",

volume = "40",

pages = "2692--2694",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "14",

}

TY - JOUR

T1 - Photochemical carbonylation of ethane under snpercritical conditions

AU - Bitterwolf, Thomas E.

AU - Kline, Dinara Lukmanova

AU - Linehan, John C.

AU - Yonker, Clement R.

AU - Shane Addleman, R.

PY - 2001/7/16

Y1 - 2001/7/16

N2 - Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.

AB - Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe3)2Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe3 and [Rh(CO)2(PMe3)Cl] or [Rh2(CO)2-(PMe3)2(μ-Cl) 2] has also been observed.

KW - Carbonylation

KW - Photocatalysis

KW - Photochemistry

KW - Rhodium

KW - Supercritical fluids

UR - http://www.scopus.com/inward/record.url?scp=0035898522&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035898522&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

DO - 10.1002/1521-3773(20010716)40:14<2692::AID-ANIE2692>3.0.CO;2-P

M3 - Article

AN - SCOPUS:0035898522

VL - 40

SP - 2692

EP - 2694

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 14

ER -