Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

Charles P. Casey; R Morris Bullock

Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

Charles P. Casey, R Morris Bullock

Pacific Northwest National Laboratory

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43 Citations (Scopus)

Abstract

Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)₄MnMo(CO)₃[η⁵-C₅H ₄P(C₆H₄-p-CH₃)₂] and formation of the phosphido-bridged metal hydride complex (CO)₄Mn[μ-P(C₆H₄-p-CH₃) ₂](μ-H)Mo(CO)₂(C₅H₅). The photolysis of (CO)₄MnMo(CO)₃[η⁵-C₅H ₄P(C₆H₄-p-CH₃)₂], 1, under 1 atm of H₂ results in the formation of (CO)₄Mn[μ-P(C₆H₄-p-CH₃) ₂](μ-H)Mo(CO)₂(C₅H₅), 2. Deprotonation of 2 by KOH gives (CO)₄Mn[μ-P(C₆H₄-p-CH₃) ₂]Mo(CO)₂(C₅H₅)^-, 3.

Original language	English
Pages (from-to)	1100-1104
Number of pages	5
Journal	Organometallics
Volume	3
Issue number	7
Publication status	Published - 1984

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Inorganic Chemistry
Organic Chemistry

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Casey, C. P., & Bullock, R. M. (1984). Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ... Organometallics, 3(7), 1100-1104.

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title = "Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...",

abstract = "Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.",

author = "Casey, {Charles P.} and Bullock, {R Morris}",

year = "1984",

language = "English",

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pages = "1100--1104",

journal = "Organometallics",

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T1 - Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

AU - Casey, Charles P.

AU - Bullock, R Morris

PY - 1984

Y1 - 1984

N2 - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.

AB - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.

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Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

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