Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

Charles P. Casey, R Morris Bullock

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43 Citations (Scopus)

Abstract

Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)35-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)35-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.

Original languageEnglish
Pages (from-to)1100-1104
Number of pages5
JournalOrganometallics
Volume3
Issue number7
Publication statusPublished - 1984

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hydrogenolysis
Hydrogenolysis
Deprotonation
metal hydrides
Photolysis
Hydrides
Phosphorus
phosphorus
Metals
photolysis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

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title = "Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...",
abstract = "Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.",
author = "Casey, {Charles P.} and Bullock, {R Morris}",
year = "1984",
language = "English",
volume = "3",
pages = "1100--1104",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "7",

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TY - JOUR

T1 - Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...

AU - Casey, Charles P.

AU - Bullock, R Morris

PY - 1984

Y1 - 1984

N2 - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.

AB - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.

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