Abstract
Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.
| Original language | English |
|---|---|
| Pages (from-to) | 1100-1104 |
| Number of pages | 5 |
| Journal | Organometallics |
| Volume | 3 |
| Issue number | 7 |
| Publication status | Published - 1984 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ... / Casey, Charles P.; Bullock, R Morris.
In: Organometallics, Vol. 3, No. 7, 1984, p. 1100-1104.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2 ...
AU - Casey, Charles P.
AU - Bullock, R Morris
PY - 1984
Y1 - 1984
N2 - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.
AB - Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.
UR - http://www.scopus.com/inward/record.url?scp=0011440479&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0011440479&partnerID=8YFLogxK
M3 - Article
VL - 3
SP - 1100
EP - 1104
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 7
ER -