Abstract
Full title: Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5). The photolysis of (CO)4MnMo(CO)3[η5-C5H 4P(C6H4-p-CH3)2], 1, under 1 atm of H2 results in the formation of (CO)4Mn[μ-P(C6H4-p-CH3) 2](μ-H)Mo(CO)2(C5H5), 2. Deprotonation of 2 by KOH gives (CO)4Mn[μ-P(C6H4-p-CH3) 2]Mo(CO)2(C5H5)-, 3.
Original language | English |
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Pages (from-to) | 1100-1104 |
Number of pages | 5 |
Journal | Organometallics |
Volume | 3 |
Issue number | 7 |
Publication status | Published - 1984 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry