Photochemically generated organometallic radicals as reducing agents

Albert E. Stiegman; Alan S Goldman; Douglas B. Leslie; David R. Tyler

Photochemically generated organometallic radicals as reducing agents

Albert E. Stiegman, Alan S Goldman, Douglas B. Leslie, David R. Tyler

Rutgers University

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru₃(CO)₁₂, CpMo(CO)₃Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.

Original language	English
Pages (from-to)	632-633
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
Publication status	Published - 1984

ASJC Scopus subject areas

Molecular Medicine

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title = "Photochemically generated organometallic radicals as reducing agents",

abstract = "Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.",

author = "Stiegman, {Albert E.} and Goldman, {Alan S} and Leslie, {Douglas B.} and Tyler, {David R.}",

year = "1984",

language = "English",

pages = "632--633",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Photochemically generated organometallic radicals as reducing agents

AU - Stiegman, Albert E.

AU - Goldman, Alan S

AU - Leslie, Douglas B.

AU - Tyler, David R.

PY - 1984

Y1 - 1984

N2 - Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.

AB - Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.

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JO - Chemical Communications

JF - Chemical Communications

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