Photochemically generated organometallic radicals as reducing agents

Albert E. Stiegman, Alan S Goldman, Douglas B. Leslie, David R. Tyler

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Irradiation of metal-metal bonded carbonyl dimers in the presence of appropriate ligands generates a class of intermediates which are powerful reducing agents; Ru3(CO)12, CpMo(CO)3Cl (Cp = cyclopentadienyl), and the ferricyanide ion were reduced in order to demonstrate the utility of these photogenerated reducing agents.

Original languageEnglish
Pages (from-to)632-633
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number10
Publication statusPublished - 1984

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Reducing Agents
Reducing agents
Organometallics
Metals
Dimers
Ligands
Irradiation
Ions
hexacyanoferrate III

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Photochemically generated organometallic radicals as reducing agents. / Stiegman, Albert E.; Goldman, Alan S; Leslie, Douglas B.; Tyler, David R.

In: Journal of the Chemical Society, Chemical Communications, No. 10, 1984, p. 632-633.

Research output: Contribution to journalArticle

Stiegman, Albert E. ; Goldman, Alan S ; Leslie, Douglas B. ; Tyler, David R. / Photochemically generated organometallic radicals as reducing agents. In: Journal of the Chemical Society, Chemical Communications. 1984 ; No. 10. pp. 632-633.
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