Abstract
The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.
| Original language | English |
|---|---|
| Pages (from-to) | 529-534 |
| Number of pages | 6 |
| Journal | European Journal of Inorganic Chemistry |
| Issue number | 2 |
| Publication status | Published - 2001 |
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Keywords
- Coordination modes
- Electrochemistry
- Heterocycles
- Photochemistry
- Ruthenium
ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Photochemically induced isomerisation of ruthenium polypyridyl complexes. / Fanni, Stefano; Weldon, Frances M.; Hammarström, Leif; Mukhtar, Emad; Browne, Wesley R.; Keyes, Tia E.; Vos, Johannes G.
In: European Journal of Inorganic Chemistry, No. 2, 2001, p. 529-534.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Photochemically induced isomerisation of ruthenium polypyridyl complexes
AU - Fanni, Stefano
AU - Weldon, Frances M.
AU - Hammarström, Leif
AU - Mukhtar, Emad
AU - Browne, Wesley R.
AU - Keyes, Tia E.
AU - Vos, Johannes G.
PY - 2001
Y1 - 2001
N2 - The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.
AB - The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.
KW - Coordination modes
KW - Electrochemistry
KW - Heterocycles
KW - Photochemistry
KW - Ruthenium
UR - http://www.scopus.com/inward/record.url?scp=0035146466&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035146466&partnerID=8YFLogxK
M3 - Article
SP - 529
EP - 534
JO - Chemische Berichte
JF - Chemische Berichte
SN - 0009-2940
IS - 2
ER -