Photochemically induced isomerisation of ruthenium polypyridyl complexes

Stefano Fanni; Frances M. Weldon; Leif Hammarström; Emad Mukhtar; Wesley R. Browne; Tia E. Keyes; Johannes G. Vos

doi:10.1002/1099-0682(200102)2001:2<529::AID-EJIC529>3.0.CO;2-V

Photochemically induced isomerisation of ruthenium polypyridyl complexes

Stefano Fanni, Frances M. Weldon, Leif Hammarström, Emad Mukhtar, Wesley R. Browne, Tia E. Keyes, Johannes G. Vos

Uppsala University

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.

Original language	English
Pages (from-to)	529-534
Number of pages	6
Journal	European Journal of Inorganic Chemistry
Issue number	2
DOIs	https://doi.org/10.1002/1099-0682(200102)2001:2<529::AID-EJIC529>3.0.CO;2-V
Publication status	Published - 2001

Keywords

Coordination modes
Electrochemistry
Heterocycles
Photochemistry
Ruthenium

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/1099-0682(200102)2001:2<529::AID-EJIC529>3.0.CO;2-V

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abstract = "The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.",

keywords = "Coordination modes, Electrochemistry, Heterocycles, Photochemistry, Ruthenium",

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T1 - Photochemically induced isomerisation of ruthenium polypyridyl complexes

AU - Fanni, Stefano

AU - Weldon, Frances M.

AU - Hammarström, Leif

AU - Mukhtar, Emad

AU - Browne, Wesley R.

AU - Keyes, Tia E.

AU - Vos, Johannes G.

PY - 2001

Y1 - 2001

N2 - The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.

AB - The synthesis and characterisation of a series of ruthenium polypyridyl complexes containing pyridyltriazole ligands in different coordination modes are described. The electrochemical and electronic properties of the compounds with respect to the coordination mode of the pyridyltriazole ligand are reported. Upon photolysis of the complex containing the 1-methyl-3-(pyridin-2-yl)-1,2,4-triazole ligand, irreversible ligand isomerisation is observed.

KW - Coordination modes

KW - Electrochemistry

KW - Heterocycles

KW - Photochemistry

KW - Ruthenium

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