Photoelectrochemical Behavior of a Molecular Ru-Based Water-Oxidation Catalyst Bound to TiO2-Protected Si Photoanodes

Roc Matheu, Ivan A. Moreno-Hernandez, Xavier Sala, Harry B. Gray, Bruce S. Brunschwig, Antoni Llobet, Nathan S Lewis

Research output: Contribution to journalArticle

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Abstract

A hybrid photoanode based on a molecular water oxidation precatalyst was prepared from TiO2-protected n- or p+-Si coated with multiwalled carbon nanotubes (CNT) and the ruthenium-based water oxidation precatalyst [RuIV(tda)(py-pyr)2(O)], 1(O) (tda2- is [2,2′:6′,2″-terpyridine]-6,6″-dicarboxylato and py-pir is 4-(pyren-1-yl)-N-(pyridin-4-ylmethyl)butanamide). The Ru complex was immobilized by π-π stacking onto CNTs that had been deposited by drop casting onto Si electrodes coated with 60 nm of amorphous TiO2 and 20 nm of a layer of sputtered C. At pH = 7 with 3 Sun illumination, the n-Si/TiO2/C/CNT/[1+1(O)] electrodes exhibited current densities of 1 mA cm-2 at 1.07 V vs NHE. The current density was maintained for >200 min at a constant potential while intermittently collecting voltammograms that indicated that over half of the Ru was still in molecular form after O2 evolution.

Original languageEnglish
Pages (from-to)11345-11348
Number of pages4
JournalJournal of the American Chemical Society
Volume139
Issue number33
DOIs
Publication statusPublished - Aug 23 2017

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Carbon Nanotubes
Electrodes
Current density
Oxidation
Catalysts
Ruthenium
Water
Multiwalled carbon nanotubes (MWCN)
Solar System
Lighting
Sun
Carbon nanotubes
Casting

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Photoelectrochemical Behavior of a Molecular Ru-Based Water-Oxidation Catalyst Bound to TiO2-Protected Si Photoanodes. / Matheu, Roc; Moreno-Hernandez, Ivan A.; Sala, Xavier; Gray, Harry B.; Brunschwig, Bruce S.; Llobet, Antoni; Lewis, Nathan S.

In: Journal of the American Chemical Society, Vol. 139, No. 33, 23.08.2017, p. 11345-11348.

Research output: Contribution to journalArticle

Matheu, Roc ; Moreno-Hernandez, Ivan A. ; Sala, Xavier ; Gray, Harry B. ; Brunschwig, Bruce S. ; Llobet, Antoni ; Lewis, Nathan S. / Photoelectrochemical Behavior of a Molecular Ru-Based Water-Oxidation Catalyst Bound to TiO2-Protected Si Photoanodes. In: Journal of the American Chemical Society. 2017 ; Vol. 139, No. 33. pp. 11345-11348.
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