Photoelectrochemical properties of chemically exfoliated MoS2

Laurie A. King, Weijie Zhao, Manish Chhowalla, D. Jason Riley, Goki Eda

Research output: Contribution to journalArticle

95 Citations (Scopus)

Abstract

Group 6 transition metal dichalcogenides (TMD) such as MoS2 are promising candidates for photocatalysis and photoelectrochemical applications. Despite their promise, scalable deposition of thin films remains a challenge for TMD-based photoanodes. Here we investigate the photoelectrochemical properties of ultra-thin films of chemically exfoliated MoS2 and its composites with TiO2 nanoparticles. We show that MoS2 monolayer films exhibit photoelectrochemical properties similar to bulk materials, generating photocurrent at excitation wavelengths above the direct band gap edge at ∼660 nm (∼1.9 eV). We also demonstrate that MoS2 monolayers adsorbed on TiO2 behave as effective photosensitizers. We find that in TiO2-MoS2 composite photoanodes, photoexcited hot electrons in MoS2 are able inject into TiO2 whilst holes are removed by the electrolyte so as to generate electrical current from incident light. Our results demonstrate the potential of solution-processed MoS2 monolayers for photoelectrochemical applications.

Original languageEnglish
Pages (from-to)8935-8941
Number of pages7
JournalJournal of Materials Chemistry A
Volume1
Issue number31
DOIs
Publication statusPublished - Aug 21 2013

Fingerprint

Monolayers
Transition metals
Photosensitizing Agents
Photosensitizers
Hot electrons
Photocatalysis
Ultrathin films
Composite materials
Photocurrents
Electrolytes
Energy gap
Nanoparticles
Thin films
Wavelength

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)
  • Materials Chemistry

Cite this

Photoelectrochemical properties of chemically exfoliated MoS2 . / King, Laurie A.; Zhao, Weijie; Chhowalla, Manish; Riley, D. Jason; Eda, Goki.

In: Journal of Materials Chemistry A, Vol. 1, No. 31, 21.08.2013, p. 8935-8941.

Research output: Contribution to journalArticle

King, Laurie A. ; Zhao, Weijie ; Chhowalla, Manish ; Riley, D. Jason ; Eda, Goki. / Photoelectrochemical properties of chemically exfoliated MoS2 In: Journal of Materials Chemistry A. 2013 ; Vol. 1, No. 31. pp. 8935-8941.
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