Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore

Julia A. Weinstein, David C. Grills, Michael Towrie, David Grills, Anthony W. Parker, Michael W. George

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Abstract

This is the first report describing the use of picosecond timeresolved infrared (TRIR) spectroscopy to probe a d8 metal chromophore, Pt(4,4′-(CO2Et)2-2,2′-bpy)Cl2: monitoring changes in the v(CO) vibrations allows for an assignment of the lowest excited state to an MLCT with an 8.7 ps lifetime.

Original languageEnglish
Pages (from-to)382-383
Number of pages2
JournalChemical Communications
Issue number4
Publication statusPublished - Feb 21 2002

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ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Weinstein, J. A., Grills, D. C., Towrie, M., Grills, D., Parker, A. W., & George, M. W. (2002). Picosecond time-resolved infrared spectroscopic investigation of excited state dynamics in a PtII diimine chromophore. Chemical Communications, (4), 382-383.