Planar versus mesoscopic perovskite microstructures

The influence of CH3NH3PbI3 morphology on charge transport and recombination dynamics

Alexander R. Pascoe, Mengjin Yang, Nikos Kopidakis, Kai Zhu, Matthew O. Reese, Gary Rumbles, Monika Fekete, Noel W. Duffy, Yi Bing Cheng

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

Perovskite solar cells (PSCs) employing planar and mesoscopic architectures have both resulted in high efficiency devices. However, there is presently a limited understanding of the inherent advantages of both systems, particularly in terms of the charge transport and recombination dynamics. In the present study we characterize the relative benefits of the two most prominent CH3NH3PbI3 morphologies, primarily through time-resolved microwave conductivity (TRMC) and time-resolved photoluminescence (TRPL) measurements. The comparatively large perovskite grains, typical of planar assemblies, exhibited higher charge mobilities and slower trap-mediated recombination compared to the mesoscopic architectures. These findings reveal the injurious influence of grain boundaries on both charge transport and recombination kinetics, and suggest an innate advantage of planar morphologies. However, through impedance spectroscopy (IS) measurements, mesoscopic architectures were found to limit the interfacial recombination at the transparent conductive oxide (TCO) substrate. The lessons learnt through the characterization measurements were subsequently utilized to produce an optimized cell morphology, resulting in a maximum conversion efficiency of 16%.

Original languageEnglish
Pages (from-to)439-452
Number of pages14
JournalNano Energy
Volume22
DOIs
Publication statusPublished - Apr 1 2016

Fingerprint

Perovskite
Charge transfer
Microstructure
Oxides
Conversion efficiency
Photoluminescence
Grain boundaries
Microwaves
Spectroscopy
Kinetics
Substrates
perovskite
Perovskite solar cells

Keywords

  • Perovskite
  • Solar cells
  • Time-resolved microwave conductivity
  • Time-resolved photoluminescence

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)
  • Electrical and Electronic Engineering

Cite this

Planar versus mesoscopic perovskite microstructures : The influence of CH3NH3PbI3 morphology on charge transport and recombination dynamics. / Pascoe, Alexander R.; Yang, Mengjin; Kopidakis, Nikos; Zhu, Kai; Reese, Matthew O.; Rumbles, Gary; Fekete, Monika; Duffy, Noel W.; Cheng, Yi Bing.

In: Nano Energy, Vol. 22, 01.04.2016, p. 439-452.

Research output: Contribution to journalArticle

Pascoe, Alexander R. ; Yang, Mengjin ; Kopidakis, Nikos ; Zhu, Kai ; Reese, Matthew O. ; Rumbles, Gary ; Fekete, Monika ; Duffy, Noel W. ; Cheng, Yi Bing. / Planar versus mesoscopic perovskite microstructures : The influence of CH3NH3PbI3 morphology on charge transport and recombination dynamics. In: Nano Energy. 2016 ; Vol. 22. pp. 439-452.
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