Plasma-assisted reduction of graphene oxide at low temperature and atmospheric pressure for flexible conductor applications

Seung Whan Lee, Cecilia Mattevi, Manish Chhowalla, R. Mohan Sankaran

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

Reduction of graphene oxide (GO) at low temperature and atmospheric pressure via plasma-assisted chemistry is demonstrated. Hydrogen gas is continuously dissociated in a microplasma to generate atomic hydrogen, which flows from the remote plasma to thin films of GO deposited on a substrate. Direct interaction with ions and other energetic species is avoided to mitigate ion-induced sputter removal or damage. The residual oxygen content and structure of the GO films after plasma treatment is systematically characterized at different temperatures and correlated to the conductivity of the films. For example, at 150 °C, we find that the plasma-reduced GO contains less than 12.5% oxygen and exhibits a sheet resistance of 4.77 × 10 4 ω/sq, as compared with thermal reduction alone, which results in 22.9% oxygen and a sheet resistance of 2.14 × 10 6 ω/sq. Overall, the effective removal of oxygen functional groups by atomic hydrogen enables large-scale applications of GO as flexible conductors to be realized.

Original languageEnglish
Pages (from-to)772-777
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume3
Issue number6
DOIs
Publication statusPublished - Mar 15 2012

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Oxides
Graphene
Atmospheric pressure
atmospheric pressure
graphene
conductors
Plasmas
oxides
Oxygen
Hydrogen
Sheet resistance
oxygen
hydrogen
Temperature
Ions
microplasmas
Functional groups
Oxide films
oxide films

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Plasma-assisted reduction of graphene oxide at low temperature and atmospheric pressure for flexible conductor applications. / Lee, Seung Whan; Mattevi, Cecilia; Chhowalla, Manish; Sankaran, R. Mohan.

In: Journal of Physical Chemistry Letters, Vol. 3, No. 6, 15.03.2012, p. 772-777.

Research output: Contribution to journalArticle

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