Abstract
A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.
| Original language | English |
|---|---|
| Pages (from-to) | 7165-7173 |
| Number of pages | 9 |
| Journal | Inorganic Chemistry |
| Volume | 48 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Aug 3 2009 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
Cite this
PM3 : A multifunctional microporous mof with recyclable framework and high h 2 binding energy. / Lan, Anjian; Li, Kunhao; Wu, Haohan; Kong, Lingzhu; Nijem, Nour; Olson, David H.; Emge, Thomas J.; Chabal, Yves J.; Langreth, David C.; Hong, Maochun; Li, Jing.
In: Inorganic Chemistry, Vol. 48, No. 15, 03.08.2009, p. 7165-7173.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - PM3
T2 - A multifunctional microporous mof with recyclable framework and high h 2 binding energy
AU - Lan, Anjian
AU - Li, Kunhao
AU - Wu, Haohan
AU - Kong, Lingzhu
AU - Nijem, Nour
AU - Olson, David H.
AU - Emge, Thomas J.
AU - Chabal, Yves J.
AU - Langreth, David C.
AU - Hong, Maochun
AU - Li, Jing
PY - 2009/8/3
Y1 - 2009/8/3
N2 - A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.
AB - A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.
UR - http://www.scopus.com/inward/record.url?scp=68249093848&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=68249093848&partnerID=8YFLogxK
U2 - 10.1021/ic9002115
DO - 10.1021/ic9002115
M3 - Article
C2 - 19722690
AN - SCOPUS:68249093848
VL - 48
SP - 7165
EP - 7173
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 15
ER -