PM3: A multifunctional microporous mof with recyclable framework and high h 2 binding energy

Anjian Lan, Kunhao Li, Haohan Wu, Lingzhu Kong, Nour Nijem, David H. Olson, Thomas J. Emge, Yves J. Chabal, David C. Langreth, Maochun Hong, Jing Li

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Abstract

A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.

Original languageEnglish
Pages (from-to)7165-7173
Number of pages9
JournalInorganic Chemistry
Volume48
Issue number15
DOIs
Publication statusPublished - Aug 3 2009

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Lan, A., Li, K., Wu, H., Kong, L., Nijem, N., Olson, D. H., Emge, T. J., Chabal, Y. J., Langreth, D. C., Hong, M., & Li, J. (2009). PM3: A multifunctional microporous mof with recyclable framework and high h 2 binding energy. Inorganic Chemistry, 48(15), 7165-7173. https://doi.org/10.1021/ic9002115