PM3: A multifunctional microporous mof with recyclable framework and high h 2 binding energy

Anjian Lan; Kunhao Li; Haohan Wu; Lingzhu Kong; Nour Nijem; David H. Olson; Thomas J. Emge; Yves J. Chabal; David C. Langreth; Maochun Hong; Jing Li

doi:10.1021/ic9002115

PM3: A multifunctional microporous mof with recyclable framework and high h ₂ binding energy

Anjian Lan, Kunhao Li, Haohan Wu, Lingzhu Kong, Nour Nijem, David H. Olson, Thomas J. Emge, Yves J. Chabal, David C. Langreth, Maochun Hong, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

103 Citations (Scopus)

Abstract

A microporous metal organic framework structure, Zn ₂(bpdc) ₂(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.

Original language	English
Pages (from-to)	7165-7173
Number of pages	9
Journal	Inorganic Chemistry
Volume	48
Issue number	15
DOIs	https://doi.org/10.1021/ic9002115
Publication status	Published - Aug 3 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic9002115

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PM3 : A multifunctional microporous mof with recyclable framework and high h ₂ binding energy. / Lan, Anjian; Li, Kunhao; Wu, Haohan; Kong, Lingzhu; Nijem, Nour; Olson, David H.; Emge, Thomas J.; Chabal, Yves J.; Langreth, David C.; Hong, Maochun; Li, Jing.

In: Inorganic Chemistry, Vol. 48, No. 15, 03.08.2009, p. 7165-7173.

Research output: Contribution to journal › Article › peer-review

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abstract = "A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.",

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AU - Lan, Anjian

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AU - Wu, Haohan

AU - Kong, Lingzhu

AU - Nijem, Nour

AU - Olson, David H.

AU - Emge, Thomas J.

AU - Chabal, Yves J.

AU - Langreth, David C.

AU - Hong, Maochun

AU - Li, Jing

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AB - A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.

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