PM3: A multifunctional microporous mof with recyclable framework and high h 2 binding energy

Anjian Lan, Kunhao Li, Haohan Wu, Lingzhu Kong, Nour Nijem, David H. Olson, Thomas J. Emge, Yves J. Chabal, David C. Langreth, Maochun Hong, Jing Li

Research output: Contribution to journalArticle

99 Citations (Scopus)

Abstract

A microporous metal organic framework structure, Zn 2(bpdc) 2(bpee)·2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the ℝ.PM series (ℝPM=Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing onedimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.

Original languageEnglish
Pages (from-to)7165-7173
Number of pages9
JournalInorganic Chemistry
Volume48
Issue number15
DOIs
Publication statusPublished - Aug 3 2009

Fingerprint

Binding energy
Hydrogen
binding energy
Adsorption
Dimethylformamide
adsorption
porous materials
hydrogen
Hydrocarbons
Density functional theory
Porous materials
Infrared spectroscopy
Quenching
Photoluminescence
hydrocarbons
Porosity
Metals
Fluorescence
quenching
Ligands

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

PM3 : A multifunctional microporous mof with recyclable framework and high h 2 binding energy. / Lan, Anjian; Li, Kunhao; Wu, Haohan; Kong, Lingzhu; Nijem, Nour; Olson, David H.; Emge, Thomas J.; Chabal, Yves J.; Langreth, David C.; Hong, Maochun; Li, Jing.

In: Inorganic Chemistry, Vol. 48, No. 15, 03.08.2009, p. 7165-7173.

Research output: Contribution to journalArticle

Lan, A, Li, K, Wu, H, Kong, L, Nijem, N, Olson, DH, Emge, TJ, Chabal, YJ, Langreth, DC, Hong, M & Li, J 2009, 'PM3: A multifunctional microporous mof with recyclable framework and high h 2 binding energy', Inorganic Chemistry, vol. 48, no. 15, pp. 7165-7173. https://doi.org/10.1021/ic9002115
Lan, Anjian ; Li, Kunhao ; Wu, Haohan ; Kong, Lingzhu ; Nijem, Nour ; Olson, David H. ; Emge, Thomas J. ; Chabal, Yves J. ; Langreth, David C. ; Hong, Maochun ; Li, Jing. / PM3 : A multifunctional microporous mof with recyclable framework and high h 2 binding energy. In: Inorganic Chemistry. 2009 ; Vol. 48, No. 15. pp. 7165-7173.
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