Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies

Peijun Guo, Yi Xia, Jue Gong, Constantinos C. Stoumpos, Kyle M. McCall, Grant C.B. Alexander, Zhiyuan Ma, Hua Zhou, David J. Gosztola, John B. Ketterson, Mercouri G Kanatzidis, Tao Xu, Maria K.Y. Chan, Richard D Schaller

Research output: Contribution to journalArticle

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Abstract

Solution-processable metal halide perovskites (MHPs) offer great promise for efficient light-harvesting and -emitting devices because of their long carrier lifetime and superior carrier transport properties. Similar to traditional oxide perovskites, MHPs exhibit strong dynamic disorders that may further impact their electronic properties. Here we investigate the coherent acoustic phonons of inorganic and organic-inorganic (hybrid) MHP single crystals (CsPbCl3, MAPbCl3, CsPbBr3, MAPbBr3, FAPbBr3, MAPbI3, and FAPbI3) using pump-probe reflection spectroscopy. We show significant phonon softening in the cubic phase of all compositions close to the cubic-to-tetragonal phase transition temperature. Such phonon softening in conjunction with strong acoustic damping is attributed to pretransitional polar fluctuations. Comparison of MHPs with different compositions show that the degree of pretransitional fluctuations is correlated with the size rather than the dipole moment of the A-site cations, and further with the size of the anions.

Original languageEnglish
Pages (from-to)2463-2469
Number of pages7
JournalACS Energy Letters
Volume2
Issue number10
DOIs
Publication statusPublished - Oct 13 2017

Fingerprint

Metal halides
Acoustics
Carrier lifetime
Carrier transport
Dipole moment
Phonons
Chemical analysis
Electronic properties
Transport properties
Oxides
Superconducting transition temperature
Anions
Cations
Negative ions
Damping
Phase transitions
Positive ions
Single crystals
Pumps
Spectroscopy

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies. / Guo, Peijun; Xia, Yi; Gong, Jue; Stoumpos, Constantinos C.; McCall, Kyle M.; Alexander, Grant C.B.; Ma, Zhiyuan; Zhou, Hua; Gosztola, David J.; Ketterson, John B.; Kanatzidis, Mercouri G; Xu, Tao; Chan, Maria K.Y.; Schaller, Richard D.

In: ACS Energy Letters, Vol. 2, No. 10, 13.10.2017, p. 2463-2469.

Research output: Contribution to journalArticle

Guo, P, Xia, Y, Gong, J, Stoumpos, CC, McCall, KM, Alexander, GCB, Ma, Z, Zhou, H, Gosztola, DJ, Ketterson, JB, Kanatzidis, MG, Xu, T, Chan, MKY & Schaller, RD 2017, 'Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies', ACS Energy Letters, vol. 2, no. 10, pp. 2463-2469. https://doi.org/10.1021/acsenergylett.7b00790
Guo P, Xia Y, Gong J, Stoumpos CC, McCall KM, Alexander GCB et al. Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies. ACS Energy Letters. 2017 Oct 13;2(10):2463-2469. https://doi.org/10.1021/acsenergylett.7b00790
Guo, Peijun ; Xia, Yi ; Gong, Jue ; Stoumpos, Constantinos C. ; McCall, Kyle M. ; Alexander, Grant C.B. ; Ma, Zhiyuan ; Zhou, Hua ; Gosztola, David J. ; Ketterson, John B. ; Kanatzidis, Mercouri G ; Xu, Tao ; Chan, Maria K.Y. ; Schaller, Richard D. / Polar Fluctuations in Metal Halide Perovskites Uncovered by Acoustic Phonon Anomalies. In: ACS Energy Letters. 2017 ; Vol. 2, No. 10. pp. 2463-2469.
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