Poly[[aquacopper(II)]-μ-adamantane-1,3-diacetato]

Denise J. Xu, Long Pan, Thomas J. Emge, Xiao Ying Huang, Jing Li

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

In the title compound, [Cu(C14H18O 4)(H2O)]n, each CuII atom bonds to four O atoms of four adamantanediacetate (ada) ligands in equatorial positions and an O atom from a water molecule in the apical position. Two adjacent Cu II atoms form a paddle-wheel unit with four ada ligands. The distance between the two Cu atoms is 2.5977 (3) Å. A crystallographic inversion center is located at the center of the Cu-Cu core. Each Cu2(ada) 4 paddle-wheel further bonds to four adjacent identical paddle-wheel units, generating a two-dimensional layered structure of Cu(ada)(H2O) with a 44 topology.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume62
Issue number4
DOIs
Publication statusPublished - Apr 2006

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Adamantane
paddles
Ligands
Atoms
wheels
Wheels
atoms
Water
ligands
topology
Topology
inversions
Molecules
water
molecules

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Poly[[aquacopper(II)]-μ-adamantane-1,3-diacetato]. / Xu, Denise J.; Pan, Long; Emge, Thomas J.; Huang, Xiao Ying; Li, Jing.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 62, No. 4, 04.2006.

Research output: Contribution to journalArticle

Xu, Denise J. ; Pan, Long ; Emge, Thomas J. ; Huang, Xiao Ying ; Li, Jing. / Poly[[aquacopper(II)]-μ-adamantane-1,3-diacetato]. In: Acta Crystallographica Section C: Crystal Structure Communications. 2006 ; Vol. 62, No. 4.
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