Polymer synthesis and organotransition metal chemistry

Robert H. Grubbs, William Tumas

Research output: Contribution to journalArticle

473 Citations (Scopus)

Abstract

Mechanistic and synthetic studies in organometallic chemistry have provided considerable insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin metathesis catalysts based on high oxidation state transition metals have opened new opportunities in polymer synthesis by providing unprecedented control in ring-opening polymerization of cyclic alkenes. The recent development of living coordinative polymerization systems has led to the preparation of a number of new, interesting materials, including block copolymers, conducting polymers or precursors, and ionophoric polymeric substrates.

Original languageEnglish
Pages (from-to)907-915
Number of pages9
JournalScience
Volume243
Issue number4893
DOIs
Publication statusPublished - 1989

ASJC Scopus subject areas

  • General

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