Abstract
Mechanistic and synthetic studies in organometallic chemistry have provided considerable insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin metathesis catalysts based on high oxidation state transition metals have opened new opportunities in polymer synthesis by providing unprecedented control in ring-opening polymerization of cyclic alkenes. The recent development of living coordinative polymerization systems has led to the preparation of a number of new, interesting materials, including block copolymers, conducting polymers or precursors, and ionophoric polymeric substrates.
| Original language | English |
|---|---|
| Pages (from-to) | 907-915 |
| Number of pages | 9 |
| Journal | Science |
| Volume | 243 |
| Issue number | 4893 |
| Publication status | Published - Feb 17 1989 |
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Cite this
Polymer synthesis and organotransition metal chemistry. / Grubbs, R. H.; Tumas, William.
In: Science, Vol. 243, No. 4893, 17.02.1989, p. 907-915.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Polymer synthesis and organotransition metal chemistry.
AU - Grubbs, R. H.
AU - Tumas, William
PY - 1989/2/17
Y1 - 1989/2/17
N2 - Mechanistic and synthetic studies in organometallic chemistry have provided considerable insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin metathesis catalysts based on high oxidation state transition metals have opened new opportunities in polymer synthesis by providing unprecedented control in ring-opening polymerization of cyclic alkenes. The recent development of living coordinative polymerization systems has led to the preparation of a number of new, interesting materials, including block copolymers, conducting polymers or precursors, and ionophoric polymeric substrates.
AB - Mechanistic and synthetic studies in organometallic chemistry have provided considerable insight into olefin metathesis and Ziegler-Natta polymerization. New homogeneous olefin metathesis catalysts based on high oxidation state transition metals have opened new opportunities in polymer synthesis by providing unprecedented control in ring-opening polymerization of cyclic alkenes. The recent development of living coordinative polymerization systems has led to the preparation of a number of new, interesting materials, including block copolymers, conducting polymers or precursors, and ionophoric polymeric substrates.
UR - http://www.scopus.com/inward/record.url?scp=0024972656&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0024972656&partnerID=8YFLogxK
M3 - Article
C2 - 2645643
AN - SCOPUS:0024972656
VL - 243
SP - 907
EP - 915
JO - Science
JF - Science
SN - 0036-8075
IS - 4893
ER -