Polymerization of anilinium ion in the van der Waals space of [TiNbO5]- and [Nb3O8]-

C. G. Wu; H. O. Marcy; D. C. DeGroot; C. R. Kannewurf; Mercouri G Kanatzidis

Polymerization of anilinium ion in the van der Waals space of [TiNbO₅]^- and [Nb₃O₈]^-

C. G. Wu, H. O. Marcy, D. C. DeGroot, C. R. Kannewurf, Mercouri G Kanatzidis

Northwestern University

Research output: Contribution to journal › Article

Abstract

Preliminary results are reported of attempts to produce intercalated conductive polymers, namely polyaniline into poorly oxidizing hosts by topotactic oxidation of intercalated anilinium ions. Polyaniline was easily identified by its characteristic IR spectrum. Charge transport, magnetic, NMRspectroscopic and scanning and transmission electron microscopic characterization of these materials are reported. Variable temperature charge transport measurements such as electric conductivity and thermopower are also reported.

Original language	English
Pages (from-to)	691
Number of pages	1
Journal	Synthetic Metals
Volume	41
Issue number	1-2
Publication status	Published - Jan 1 1991

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ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Materials Chemistry
Polymers and Plastics

Cite this

Wu, C. G., Marcy, H. O., DeGroot, D. C., Kannewurf, C. R., & Kanatzidis, M. G. (1991). Polymerization of anilinium ion in the van der Waals space of [TiNbO₅]^- and [Nb₃O₈]^- Synthetic Metals, 41(1-2), 691.

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abstract = "Preliminary results are reported of attempts to produce intercalated conductive polymers, namely polyaniline into poorly oxidizing hosts by topotactic oxidation of intercalated anilinium ions. Polyaniline was easily identified by its characteristic IR spectrum. Charge transport, magnetic, NMRspectroscopic and scanning and transmission electron microscopic characterization of these materials are reported. Variable temperature charge transport measurements such as electric conductivity and thermopower are also reported.",

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