Polymerization of anilinium ion in the van der Waals space of [TiNbO5]- and [Nb3O8]-

C. G. Wu, H. O. Marcy, D. C. DeGroot, C. R. Kannewurf, Mercouri G Kanatzidis

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Abstract

Preliminary results are reported of attempts to produce intercalated conductive polymers, namely polyaniline into poorly oxidizing hosts by topotactic oxidation of intercalated anilinium ions. Polyaniline was easily identified by its characteristic IR spectrum. Charge transport, magnetic, NMRspectroscopic and scanning and transmission electron microscopic characterization of these materials are reported. Variable temperature charge transport measurements such as electric conductivity and thermopower are also reported.

Original languageEnglish
Pages (from-to)691
Number of pages1
JournalSynthetic Metals
Volume41
Issue number1-2
Publication statusPublished - Jan 1 1991

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Polymers and Plastics

Cite this

Wu, C. G., Marcy, H. O., DeGroot, D. C., Kannewurf, C. R., & Kanatzidis, M. G. (1991). Polymerization of anilinium ion in the van der Waals space of [TiNbO5]- and [Nb3O8]- Synthetic Metals, 41(1-2), 691.