Polymorphism in Li2Mo4O13 revisited

Jared P. Smit, Peter C Stair, Kenneth R Poeppelmeier

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

Original languageEnglish
Pages (from-to)521-525
Number of pages5
JournalCrystal Growth and Design
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 2007

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ASJC Scopus subject areas

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  • Condensed Matter Physics

Cite this

Polymorphism in Li2Mo4O13 revisited. / Smit, Jared P.; Stair, Peter C; Poeppelmeier, Kenneth R.

In: Crystal Growth and Design, Vol. 7, No. 3, 03.2007, p. 521-525.

Research output: Contribution to journal › Article

Smit, JP, Stair, PC & Poeppelmeier, KR 2007, 'Polymorphism in Li2Mo4O13 revisited', Crystal Growth and Design, vol. 7, no. 3, pp. 521-525. https://doi.org/10.1021/cg060576l
Smit JP, Stair PC, Poeppelmeier KR. Polymorphism in Li2Mo4O13 revisited. Crystal Growth and Design. 2007 Mar;7(3):521-525. https://doi.org/10.1021/cg060576l
Smit, Jared P. ; Stair, Peter C ; Poeppelmeier, Kenneth R. / Polymorphism in Li2Mo4O13 revisited. In: Crystal Growth and Design. 2007 ; Vol. 7, No. 3. pp. 521-525.
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AB - The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

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