Polymorphism in Li2Mo4O13 revisited

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

Original languageEnglish
Pages (from-to)521-525
Number of pages5
JournalCrystal Growth and Design
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 2007

Fingerprint

polymorphism
Polymorphism
Oxygen
oxygen
cells

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Polymorphism in Li2Mo4O13 revisited. / Smit, Jared P.; Stair, Peter C; Poeppelmeier, Kenneth R.

In: Crystal Growth and Design, Vol. 7, No. 3, 03.2007, p. 521-525.

Research output: Contribution to journalArticle

@article{e38c142b78fa498397bcb297a39ceb72,
title = "Polymorphism in Li2Mo4O13 revisited",
abstract = "The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) {\AA}, b = 21.2814(13) {\AA}, c = 8.5950(5) {\AA}, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.",
author = "Smit, {Jared P.} and Stair, {Peter C} and Poeppelmeier, {Kenneth R}",
year = "2007",
month = "3",
doi = "10.1021/cg060576l",
language = "English",
volume = "7",
pages = "521--525",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "3",

}

TY - JOUR

T1 - Polymorphism in Li2Mo4O13 revisited

AU - Smit, Jared P.

AU - Stair, Peter C

AU - Poeppelmeier, Kenneth R

PY - 2007/3

Y1 - 2007/3

N2 - The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

AB - The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

UR - http://www.scopus.com/inward/record.url?scp=33947514698&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33947514698&partnerID=8YFLogxK

U2 - 10.1021/cg060576l

DO - 10.1021/cg060576l

M3 - Article

VL - 7

SP - 521

EP - 525

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 3

ER -