Polymorphism in Li2Mo4O13 revisited

Jared P. Smit; Peter C. Stair; Kenneth R. Poeppelmeier

doi:10.1021/cg060576l

Polymorphism in Li₂Mo₄O₁₃ revisited

Jared P. Smit, Peter C. Stair, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The structure of M-Li₂Mo₄O₁₃ has been determined. M-Li₂Mo₄O₁₃ crystallizes in the monoclinic and noncentrosymmetric space group P2₁ (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li₂Mo₄O₁₃ is one of three polymorphs and all three phases are Li-Mo cosubstituted V₆O ₁₃ homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

Original language	English
Pages (from-to)	521-525
Number of pages	5
Journal	Crystal Growth and Design
Volume	7
Issue number	3
DOIs	https://doi.org/10.1021/cg060576l
Publication status	Published - Mar 2007

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Polymorphism in Li2Mo4O13 revisited",

abstract = "The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) {\AA}, b = 21.2814(13) {\AA}, c = 8.5950(5) {\AA}, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.",

author = "Smit, {Jared P.} and Stair, {Peter C.} and Poeppelmeier, {Kenneth R.}",

year = "2007",

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doi = "10.1021/cg060576l",

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T1 - Polymorphism in Li2Mo4O13 revisited

AU - Smit, Jared P.

AU - Stair, Peter C.

AU - Poeppelmeier, Kenneth R.

PY - 2007/3

Y1 - 2007/3

N2 - The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

AB - The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

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