Polymorphism in phthalocyanine thin films: Mechanism of the α → β transition

S. Heutz, S. M. Bayliss, R. L. Middleton, Gary Rumbles, T. S. Jones

Research output: Contribution to journalArticle

76 Citations (Scopus)

Abstract

Two different polymorphic forms of free base phthalocyanine films have been grown on glass substrates by ultrahigh vacuum organic molecular beam deposition. Postgrowth annealing of films grown at room temperature leads to transformation from the a to the β1 phase. The effects of annealing lead to a number of transition states whose morphological, structural, and spectroscopic properties can be identified using atomic force and optical interference microscopy, X-ray diffraction, and Raman and electronic absorption spectroscopy. Detailed morphological studies indicate that the transition occurs via a discrete number of nucleations and is preceded by an elongation of the a crystallites. Quantitative analysis of the crystallites and domain size shows that the individual β1 crystals grow but are confined to domains of similar orientation. The film thickness plays a critical role and three regimes have been identified. The α → β1 transformation is only complete for films thicker than ∼940 Å, and thick films lead to a higher degree of orientation and larger domains.

Original languageEnglish
Pages (from-to)7124-7129
Number of pages6
JournalJournal of Physical Chemistry B
Volume104
Issue number30
Publication statusPublished - Aug 3 2000

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polymorphism
Polymorphism
Crystallites
Thick films
Annealing
Light interference
Thin films
crystallites
thick films
Molecular beams
Ultrahigh vacuum
thin films
Absorption spectroscopy
Film thickness
Elongation
Microscopic examination
annealing
Nucleation
X ray diffraction
Glass

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Engineering(all)

Cite this

Heutz, S., Bayliss, S. M., Middleton, R. L., Rumbles, G., & Jones, T. S. (2000). Polymorphism in phthalocyanine thin films: Mechanism of the α → β transition. Journal of Physical Chemistry B, 104(30), 7124-7129.

Polymorphism in phthalocyanine thin films : Mechanism of the α → β transition. / Heutz, S.; Bayliss, S. M.; Middleton, R. L.; Rumbles, Gary; Jones, T. S.

In: Journal of Physical Chemistry B, Vol. 104, No. 30, 03.08.2000, p. 7124-7129.

Research output: Contribution to journalArticle

Heutz, S, Bayliss, SM, Middleton, RL, Rumbles, G & Jones, TS 2000, 'Polymorphism in phthalocyanine thin films: Mechanism of the α → β transition', Journal of Physical Chemistry B, vol. 104, no. 30, pp. 7124-7129.
Heutz, S. ; Bayliss, S. M. ; Middleton, R. L. ; Rumbles, Gary ; Jones, T. S. / Polymorphism in phthalocyanine thin films : Mechanism of the α → β transition. In: Journal of Physical Chemistry B. 2000 ; Vol. 104, No. 30. pp. 7124-7129.
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