Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

Amy L. Kopf, Paul A. Maggard, Charlotte L. Stern, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - Apr 2005

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2,2'-Dipyridyl
Nickel
Copper
apexes
Metals
nickel
Ligands
copper
chromates
inversions
ligands
symmetry
metals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

@article{78aa506208ba4baaa0d6d089845c31f3,
title = "Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]",
abstract = "The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.",
author = "Kopf, {Amy L.} and Maggard, {Paul A.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R}",
year = "2005",
month = "4",
doi = "10.1107/S0108270105001605",
language = "English",
volume = "61",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "4",

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TY - JOUR

T1 - Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N

T2 - N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

AU - Kopf, Amy L.

AU - Maggard, Paul A.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R

PY - 2005/4

Y1 - 2005/4

N2 - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

AB - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

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