Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

Amy L. Kopf, Paul A. Maggard, Charlotte L. Stern, Kenneth R. Poeppelmeier

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

Original languageEnglish
Pages (from-to)m165-m168
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - Apr 1 2005

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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