Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

Amy L. Kopf, Paul A. Maggard, Charlotte L. Stern, Kenneth R Poeppelmeier

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - Apr 2005

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2,2'-Dipyridyl
Nickel
Copper
apexes
Metals
nickel
Ligands
copper
chromates
inversions
ligands
symmetry
metals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

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Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N : N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]. / Kopf, Amy L.; Maggard, Paul A.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 4, 04.2005.

Research output: Contribution to journal › Article

Kopf, AL, Maggard, PA, Stern, CL & Poeppelmeier, KR 2005, 'Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]', Acta Crystallographica Section C: Crystal Structure Communications, vol. 61, no. 4. https://doi.org/10.1107/S0108270105001605
Kopf AL, Maggard PA, Stern CL, Poeppelmeier KR. Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]. Acta Crystallographica Section C: Crystal Structure Communications. 2005 Apr;61(4). https://doi.org/10.1107/S0108270105001605
Kopf, Amy L. ; Maggard, Paul A. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N : N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]. In: Acta Crystallographica Section C: Crystal Structure Communications. 2005 ; Vol. 61, No. 4.
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abstract = "The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.",
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AB - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

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