Abstract
The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.
| Original language | English |
|---|---|
| Pages (from-to) | m165-m168 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 61 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Apr 1 2005 |
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
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Cite this
Kopf, A. L., Maggard, P. A., Stern, C. L., & Poeppelmeier, K. R. (2005). Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]. Acta Crystallographica Section C: Crystal Structure Communications, 61(4), m165-m168. https://doi.org/10.1107/S0108270105001605