TY - JOUR
T1 - Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N
T2 - N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]
AU - Kopf, Amy L.
AU - Maggard, Paul A.
AU - Stern, Charlotte L.
AU - Poeppelmeier, Kenneth R.
PY - 2005/4/1
Y1 - 2005/4/1
N2 - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.
AB - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.
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U2 - 10.1107/S0108270105001605
DO - 10.1107/S0108270105001605
M3 - Article
AN - SCOPUS:30744458818
VL - 61
SP - m165-m168
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -