Polyselenophenes

Asit Patra, Michael Bendikov

Research output: Contribution to journalArticle

245 Citations (Scopus)

Abstract

Conducting polymers are an interdisciplinary research area involving close collaborations between chemists, material scientists, physicists, and engineers. The field has developed during the last 30 years due to an interest in academic research as well as in possible commercial applications. Much research has been performed on conjugated polyacetylenes, polythiophenes, polypyrroles, polyphenylenes, poly(p-phenylene vinylene)s and other conducting polymers. Polythiophenes are the most studied conjugated polymers, yet, despite the thousands of papers published on polythiophene and its derivatives, very little is known about its close analogue, polyselenophene. Polyselenophenes should have some advantages over polythiophenes, however no reasonably conducting polyselenophene was reported until recently. Oligo- and polyselenophenes have a more quinoid character, lower band gap, and, importantly, they are more difficult to twist than oligo- and polythiophenes. Parent polyselenophene has been studied, while polyselenophene derivatives were practically unexplored until lately. Significant progress in polyselenophenes has been reported over the last two years, leading to the availability of promising polyselenophene materials. This feature article gives a general overview of polyselenophenes and highlights recent progress in this field, mostly from the authors' own work.

Original languageEnglish
Pages (from-to)422-433
Number of pages12
JournalJournal of Materials Chemistry
Volume20
Issue number3
DOIs
Publication statusPublished - 2010

Fingerprint

Polymers
Conducting polymers
Polyacetylenes
Derivatives
Conjugated polymers
Polypyrroles
Energy gap
polythiophene
Availability
Engineers
polypyrrole
poly(4-phenylenevinylene)

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemistry(all)

Cite this

Polyselenophenes. / Patra, Asit; Bendikov, Michael.

In: Journal of Materials Chemistry, Vol. 20, No. 3, 2010, p. 422-433.

Research output: Contribution to journalArticle

Patra, Asit ; Bendikov, Michael. / Polyselenophenes. In: Journal of Materials Chemistry. 2010 ; Vol. 20, No. 3. pp. 422-433.
@article{ea0bc4629a6044cbb065639efb406b50,
title = "Polyselenophenes",
abstract = "Conducting polymers are an interdisciplinary research area involving close collaborations between chemists, material scientists, physicists, and engineers. The field has developed during the last 30 years due to an interest in academic research as well as in possible commercial applications. Much research has been performed on conjugated polyacetylenes, polythiophenes, polypyrroles, polyphenylenes, poly(p-phenylene vinylene)s and other conducting polymers. Polythiophenes are the most studied conjugated polymers, yet, despite the thousands of papers published on polythiophene and its derivatives, very little is known about its close analogue, polyselenophene. Polyselenophenes should have some advantages over polythiophenes, however no reasonably conducting polyselenophene was reported until recently. Oligo- and polyselenophenes have a more quinoid character, lower band gap, and, importantly, they are more difficult to twist than oligo- and polythiophenes. Parent polyselenophene has been studied, while polyselenophene derivatives were practically unexplored until lately. Significant progress in polyselenophenes has been reported over the last two years, leading to the availability of promising polyselenophene materials. This feature article gives a general overview of polyselenophenes and highlights recent progress in this field, mostly from the authors' own work.",
author = "Asit Patra and Michael Bendikov",
year = "2010",
doi = "10.1039/b908983g",
language = "English",
volume = "20",
pages = "422--433",
journal = "Journal of Materials Chemistry",
issn = "0959-9428",
publisher = "Royal Society of Chemistry",
number = "3",

}

TY - JOUR

T1 - Polyselenophenes

AU - Patra, Asit

AU - Bendikov, Michael

PY - 2010

Y1 - 2010

N2 - Conducting polymers are an interdisciplinary research area involving close collaborations between chemists, material scientists, physicists, and engineers. The field has developed during the last 30 years due to an interest in academic research as well as in possible commercial applications. Much research has been performed on conjugated polyacetylenes, polythiophenes, polypyrroles, polyphenylenes, poly(p-phenylene vinylene)s and other conducting polymers. Polythiophenes are the most studied conjugated polymers, yet, despite the thousands of papers published on polythiophene and its derivatives, very little is known about its close analogue, polyselenophene. Polyselenophenes should have some advantages over polythiophenes, however no reasonably conducting polyselenophene was reported until recently. Oligo- and polyselenophenes have a more quinoid character, lower band gap, and, importantly, they are more difficult to twist than oligo- and polythiophenes. Parent polyselenophene has been studied, while polyselenophene derivatives were practically unexplored until lately. Significant progress in polyselenophenes has been reported over the last two years, leading to the availability of promising polyselenophene materials. This feature article gives a general overview of polyselenophenes and highlights recent progress in this field, mostly from the authors' own work.

AB - Conducting polymers are an interdisciplinary research area involving close collaborations between chemists, material scientists, physicists, and engineers. The field has developed during the last 30 years due to an interest in academic research as well as in possible commercial applications. Much research has been performed on conjugated polyacetylenes, polythiophenes, polypyrroles, polyphenylenes, poly(p-phenylene vinylene)s and other conducting polymers. Polythiophenes are the most studied conjugated polymers, yet, despite the thousands of papers published on polythiophene and its derivatives, very little is known about its close analogue, polyselenophene. Polyselenophenes should have some advantages over polythiophenes, however no reasonably conducting polyselenophene was reported until recently. Oligo- and polyselenophenes have a more quinoid character, lower band gap, and, importantly, they are more difficult to twist than oligo- and polythiophenes. Parent polyselenophene has been studied, while polyselenophene derivatives were practically unexplored until lately. Significant progress in polyselenophenes has been reported over the last two years, leading to the availability of promising polyselenophene materials. This feature article gives a general overview of polyselenophenes and highlights recent progress in this field, mostly from the authors' own work.

UR - http://www.scopus.com/inward/record.url?scp=72949096758&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=72949096758&partnerID=8YFLogxK

U2 - 10.1039/b908983g

DO - 10.1039/b908983g

M3 - Article

AN - SCOPUS:72949096758

VL - 20

SP - 422

EP - 433

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

IS - 3

ER -