Abstract
Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.
| Original language | English |
|---|---|
| Pages (from-to) | 266-271 |
| Number of pages | 6 |
| Journal | Inorganica Chimica Acta |
| Volume | 364 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Dec 15 2010 |
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Keywords
- Carboranes
- Coordination polymers
- MOFs
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design. / Spokoyny, Alexander M.; Farha, Omar K.; Mulfort, Karen L.; Hupp, Joseph T; Mirkin, Chad A.
In: Inorganica Chimica Acta, Vol. 364, No. 1, 15.12.2010, p. 266-271.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design
AU - Spokoyny, Alexander M.
AU - Farha, Omar K.
AU - Mulfort, Karen L.
AU - Hupp, Joseph T
AU - Mirkin, Chad A.
PY - 2010/12/15
Y1 - 2010/12/15
N2 - Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.
AB - Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.
KW - Carboranes
KW - Coordination polymers
KW - MOFs
UR - http://www.scopus.com/inward/record.url?scp=78649750584&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78649750584&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2010.08.007
DO - 10.1016/j.ica.2010.08.007
M3 - Article
AN - SCOPUS:78649750584
VL - 364
SP - 266
EP - 271
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1
ER -