Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

Suzanne Bélanger; Joseph T. Hupp

doi:10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4

Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

Suzanne Bélanger, Joseph T. Hupp

Northwestern University

Research output: Contribution to journal › Article › peer-review

95 Citations (Scopus)

Abstract

Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

Original language	English
Pages (from-to)	2222-2224
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	15
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4
Publication status	Published - Aug 2 1999

Keywords

Electrochemistry
Mesoporosity
Metallacycles
Nanostructures
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4

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Cite this

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abstract = "Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.",

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AU - Hupp, Joseph T.

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N2 - Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

AB - Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

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KW - Nanostructures

KW - Supramolecular chemistry

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