Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So; M. Hassan Beyzavi; Rohan Sawhney; Osama Shekhah; Mohamed Eddaoudi; Salih S. Al-Juaid; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c4cc05727a

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih S. Al-Juaid, Joseph T. Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Original language	English
Pages (from-to)	85-88
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	1
DOIs	https://doi.org/10.1039/c4cc05727a
Publication status	Published - Jan 4 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c4cc05727a

Fingerprint Dive into the research topics of 'Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination'. Together they form a unique fingerprint.

Cite this

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination. / So, Monica C.; Beyzavi, M. Hassan; Sawhney, Rohan; Shekhah, Osama; Eddaoudi, Mohamed; Al-Juaid, Salih S.; Hupp, Joseph T.; Farha, Omar K.

In: Chemical Communications, Vol. 51, No. 1, 04.01.2015, p. 85-88.

Research output: Contribution to journal › Article › peer-review

@article{a11bbb09b0a849f2acb46501ac3c1cfc,

title = "Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination",

abstract = "Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.",

author = "So, {Monica C.} and Beyzavi, {M. Hassan} and Rohan Sawhney and Osama Shekhah and Mohamed Eddaoudi and Al-Juaid, {Salih S.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

year = "2015",

month = jan,

day = "4",

doi = "10.1039/c4cc05727a",

language = "English",

volume = "51",

pages = "85--88",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

AU - So, Monica C.

AU - Beyzavi, M. Hassan

AU - Sawhney, Rohan

AU - Shekhah, Osama

AU - Eddaoudi, Mohamed

AU - Al-Juaid, Salih S.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2015/1/4

Y1 - 2015/1/4

N2 - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

AB - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

UR - http://www.scopus.com/inward/record.url?scp=84915750591&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84915750591&partnerID=8YFLogxK

U2 - 10.1039/c4cc05727a

DO - 10.1039/c4cc05727a

M3 - Article

AN - SCOPUS:84915750591

VL - 51

SP - 85

EP - 88

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 1

ER -