Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So; M. Hassan Beyzavi; Rohan Sawhney; Osama Shekhah; Mohamed Eddaoudi; Salih S. Al-Juaid; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c4cc05727a

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih S. Al-Juaid, Joseph T. Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Original language	English
Pages (from-to)	85-88
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	1
DOIs	https://doi.org/10.1039/c4cc05727a
Publication status	Published - Jan 4 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination. / So, Monica C.; Beyzavi, M. Hassan; Sawhney, Rohan; Shekhah, Osama; Eddaoudi, Mohamed; Al-Juaid, Salih S.; Hupp, Joseph T.; Farha, Omar K.

In: Chemical Communications, Vol. 51, No. 1, 04.01.2015, p. 85-88.

Research output: Contribution to journal › Article › peer-review

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