Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials

Abraham M. Shultz, Amy A. Sarjeant, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

163 Citations (Scopus)

Abstract

A series of metallosalen-based metal-organic frameworks (MOFs) have been prepared by the post-synthesis modification of MnIIISO-MOF, a Mn 3+(salen)-based MOF. Treatment of MnIIISO-MOF with H 2O2 effects the removal of the Mn3+ ions from the salen struts, which can then be remetalated with a variety of metal precursors to form isostructural MSO-MOF materials. The presence of the new metallosalen struts in MSO-MOF was fully confirmed by ICP-OES, MALDI-TOF MS, PXRD, and TGA. Furthermore, the remetalated MnIISO-MOF material displays similar catalytic activity and porosity to the parent MOF.

Original languageEnglish
Pages (from-to)13252-13255
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number34
DOIs
Publication statusPublished - Aug 31 2011

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Metals
Struts
Porosity
Matrix-Assisted Laser Desorption-Ionization Mass Spectrometry
Catalyst activity
Ions

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials. / Shultz, Abraham M.; Sarjeant, Amy A.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Journal of the American Chemical Society, Vol. 133, No. 34, 31.08.2011, p. 13252-13255.

Research output: Contribution to journalArticle

Shultz, Abraham M. ; Sarjeant, Amy A. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Post-synthesis modification of a metal-organic framework to form metallosalen-containing MOF materials. In: Journal of the American Chemical Society. 2011 ; Vol. 133, No. 34. pp. 13252-13255.
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