Preparation and crystal structure of a selenoantimonate [Fe(en) 3][enH]SbSe 4

Monique R. Girard, Jing Li, Davide M. Proserpio

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Low temperature synthesis has produced a new selenoantimonate, [Fe(en) 3][enH]SbSe 4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å 3 and Z = 2. Structural refinement using 2850 reflections (F o > 4((F o)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe 4) 3- and metal coordination complex [Fe(en) 3] 2+ and [enH] + cations. The metal complex is present with 72% as lel 2ob conformer and 28% as lel 3 conformer.

Original languageEnglish
Pages (from-to)231-236
Number of pages6
JournalMain Group Metal Chemistry
Volume21
Issue number4
Publication statusPublished - 1998

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ethylenediamine
Coordination Complexes
Crystal structure
preparation
Crystals
crystal structure
Metal complexes
metals
crystals
Anions
Cations
Negative ions
Positive ions
Metals
anions
cations
synthesis
cells
Temperature

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Preparation and crystal structure of a selenoantimonate [Fe(en) 3][enH]SbSe 4 . / Girard, Monique R.; Li, Jing; Proserpio, Davide M.

In: Main Group Metal Chemistry, Vol. 21, No. 4, 1998, p. 231-236.

Research output: Contribution to journalArticle

Girard, Monique R. ; Li, Jing ; Proserpio, Davide M. / Preparation and crystal structure of a selenoantimonate [Fe(en) 3][enH]SbSe 4 In: Main Group Metal Chemistry. 1998 ; Vol. 21, No. 4. pp. 231-236.
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