Preparation and crystal structure of a selenoantimonate [Fe(en)3][enH]SbSe4

Monique R. Girard; Jing Li; Davide M. Proserpio

doi:10.1515/MGMC.1998.21.4.231

Preparation and crystal structure of a selenoantimonate [Fe(en)₃][enH]SbSe₄

Monique R. Girard, Jing Li, Davide M. Proserpio

Rutgers University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

Low temperature synthesis has produced a new selenoantimonate, [Fe(en)₃][enH]SbSe₄ (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å³ and Z = 2. Structural refinement using 2850 reflections (F_o > 4((F_o)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe₄)^3- and metal coordination complex [Fe(en)₃]²⁺ and [enH]⁺ cations. The metal complex is present with 72% as lel₂ob conformer and 28% as lel₃ conformer.

Original language	English
Pages (from-to)	231-236
Number of pages	6
Journal	Main Group Metal Chemistry
Volume	21
Issue number	4
DOIs	https://doi.org/10.1515/MGMC.1998.21.4.231
Publication status	Published - 1998

ASJC Scopus subject areas

Chemistry(all)
Condensed Matter Physics
Metals and Alloys
Materials Chemistry

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@article{1371ac0abdc344ada079299e3b8a03e9,

title = "Preparation and crystal structure of a selenoantimonate [Fe(en)3][enH]SbSe4",

abstract = "Low temperature synthesis has produced a new selenoantimonate, [Fe(en)3][enH]SbSe4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) {\AA}, b = 9.679(2) {\AA}, c = 14.345(4) {\AA}, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) {\AA}3 and Z = 2. Structural refinement using 2850 reflections (Fo > 4((Fo)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe4)3- and metal coordination complex [Fe(en)3]2+ and [enH]+ cations. The metal complex is present with 72% as lel2ob conformer and 28% as lel3 conformer.",

author = "Girard, {Monique R.} and Jing Li and Proserpio, {Davide M.}",

note = "Funding Information: Support from the National Science foundation via Grant DMR-9553066 is gratefully acknowledged. This work was also partially supported by a Petroleum Research Fund (Type-B) administrated by the American Chemical Society. JL is grateful to the Camille and Henry Dreyfus Foundation for the Henry Dreyfus Teacher-Scholar Award.",

year = "1998",

doi = "10.1515/MGMC.1998.21.4.231",

language = "English",

volume = "21",

pages = "231--236",

journal = "Reviews on silicon, germanium, tin and lead compounds",

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T1 - Preparation and crystal structure of a selenoantimonate [Fe(en)3][enH]SbSe4

AU - Girard, Monique R.

AU - Li, Jing

AU - Proserpio, Davide M.

N1 - Funding Information: Support from the National Science foundation via Grant DMR-9553066 is gratefully acknowledged. This work was also partially supported by a Petroleum Research Fund (Type-B) administrated by the American Chemical Society. JL is grateful to the Camille and Henry Dreyfus Foundation for the Henry Dreyfus Teacher-Scholar Award.

PY - 1998

Y1 - 1998

N2 - Low temperature synthesis has produced a new selenoantimonate, [Fe(en)3][enH]SbSe4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å3 and Z = 2. Structural refinement using 2850 reflections (Fo > 4((Fo)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe4)3- and metal coordination complex [Fe(en)3]2+ and [enH]+ cations. The metal complex is present with 72% as lel2ob conformer and 28% as lel3 conformer.

AB - Low temperature synthesis has produced a new selenoantimonate, [Fe(en)3][enH]SbSe4 (I). Crystals of I were grown at 160°C in ethylenediamine solution. Compound I crystallizes in triclinic crystal system, space group P-1 (no. 2), with unit cell constants a = 8.916(2) Å, b = 9.679(2) Å, c = 14.345(4) Å, α = 104.71(3)°, β = 92.51(2)°, γ = 110.14(2)°, V = 1112.4(5) Å3 and Z = 2. Structural refinement using 2850 reflections (Fo > 4((Fo)] and 204 variables resulted in 0.04 for R1 and 0.06 for wR2. I contains molecular Zintl anions (SbSe4)3- and metal coordination complex [Fe(en)3]2+ and [enH]+ cations. The metal complex is present with 72% as lel2ob conformer and 28% as lel3 conformer.

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