Abstract
The compound dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III), Fe(C16H12NO2)Cl2(C2H 5OH), has been prepared, and its structure has been determined crystallographically. The compound was prepared by the reaction of iron(II) chloride with α-aminoacetophenone in the presence of air. The structure consists of octahedral iron(III) coordinated by two chlorides, an ethanol, and a tridentate ligand derived from two molecules of α-aminoacetophenone by oxidation and condensation. The two five-membered rings of the ligand are virtually identical. The compound crystallizes in monoclinic space group C2/c with eight formula units in a unit cell of dimensions a = 29.606 (8) Å, b = 6.689 (1) Å, c = 20.627 (6) Å, β = 114.70 (2)°, ρcalcd = 1.51 g/cm3, and ρobsd = 1.51 g/cm3. The structure was solved by Patterson methods, and least-squares refinement converged at final values of R = 0.066 and Rw = 0.045 for 1729 reflections with I ≥ 2σ(I).
| Original language | English |
|---|---|
| Pages (from-to) | 3571-3574 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry |
| Volume | 17 |
| Issue number | 12 |
| Publication status | Published - 1978 |
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- Inorganic Chemistry
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Preparation, properties, and crystal structure of dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III). / Bertrand, J. A.; Fujita, Etsuko; Eller, P. Gary; VanDerveer, D. G.
In: Inorganic Chemistry, Vol. 17, No. 12, 1978, p. 3571-3574.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Preparation, properties, and crystal structure of dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III)
AU - Bertrand, J. A.
AU - Fujita, Etsuko
AU - Eller, P. Gary
AU - VanDerveer, D. G.
PY - 1978
Y1 - 1978
N2 - The compound dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III), Fe(C16H12NO2)Cl2(C2H 5OH), has been prepared, and its structure has been determined crystallographically. The compound was prepared by the reaction of iron(II) chloride with α-aminoacetophenone in the presence of air. The structure consists of octahedral iron(III) coordinated by two chlorides, an ethanol, and a tridentate ligand derived from two molecules of α-aminoacetophenone by oxidation and condensation. The two five-membered rings of the ligand are virtually identical. The compound crystallizes in monoclinic space group C2/c with eight formula units in a unit cell of dimensions a = 29.606 (8) Å, b = 6.689 (1) Å, c = 20.627 (6) Å, β = 114.70 (2)°, ρcalcd = 1.51 g/cm3, and ρobsd = 1.51 g/cm3. The structure was solved by Patterson methods, and least-squares refinement converged at final values of R = 0.066 and Rw = 0.045 for 1729 reflections with I ≥ 2σ(I).
AB - The compound dichloro(1,3-dibenzoyl-2-azapropenato)(ethanol)iron(III), Fe(C16H12NO2)Cl2(C2H 5OH), has been prepared, and its structure has been determined crystallographically. The compound was prepared by the reaction of iron(II) chloride with α-aminoacetophenone in the presence of air. The structure consists of octahedral iron(III) coordinated by two chlorides, an ethanol, and a tridentate ligand derived from two molecules of α-aminoacetophenone by oxidation and condensation. The two five-membered rings of the ligand are virtually identical. The compound crystallizes in monoclinic space group C2/c with eight formula units in a unit cell of dimensions a = 29.606 (8) Å, b = 6.689 (1) Å, c = 20.627 (6) Å, β = 114.70 (2)°, ρcalcd = 1.51 g/cm3, and ρobsd = 1.51 g/cm3. The structure was solved by Patterson methods, and least-squares refinement converged at final values of R = 0.066 and Rw = 0.045 for 1729 reflections with I ≥ 2σ(I).
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UR - http://www.scopus.com/inward/citedby.url?scp=0012582049&partnerID=8YFLogxK
M3 - Article
VL - 17
SP - 3571
EP - 3574
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 12
ER -