Principles and implementations of dissipative (dynamic) self-assembly

Marcin Fialkowski, Kyle J M Bishop, Rafal Klajn, Stoyan K. Smoukov, Christopher J. Campbell, Bartosz A. Grzybowski

Research output: Contribution to journalArticle

175 Citations (Scopus)

Abstract

Dynamic self-assembly (DySA) processes occurring outside of thermodynamic equilibrium underlie many forms of adaptive and intellligent behaviors in natural systems. Relatively little, however, is known about the principles that govern DySA and the ways in which it can be extended to artificial ensembles. This article discusses recent advances in both the theory and the practice of nonequilibrium self-assembly. It is argued that a union of ideas from thermodynamics and dynamic systems' theory can provide a general description of DySA. In parallel, heuristic design rules can be used to construct DySA systems of increasing complexities based on a variety of suitable interactions/ potentials on length scales from nanoscopic to macroscopic. Applications of these rules to magnetohydrodynamic DySA are also discussed.

Original languageEnglish
Pages (from-to)2482-2496
Number of pages15
JournalJournal of Physical Chemistry B
Volume110
Issue number6
DOIs
Publication statusPublished - Feb 16 2006

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Self assembly
self assembly
Thermodynamics
unions
System theory
thermodynamic equilibrium
Magnetohydrodynamics
magnetohydrodynamics
Dynamical systems
thermodynamics
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Fialkowski, M., Bishop, K. J. M., Klajn, R., Smoukov, S. K., Campbell, C. J., & Grzybowski, B. A. (2006). Principles and implementations of dissipative (dynamic) self-assembly. Journal of Physical Chemistry B, 110(6), 2482-2496. https://doi.org/10.1021/jp054153q

Principles and implementations of dissipative (dynamic) self-assembly. / Fialkowski, Marcin; Bishop, Kyle J M; Klajn, Rafal; Smoukov, Stoyan K.; Campbell, Christopher J.; Grzybowski, Bartosz A.

In: Journal of Physical Chemistry B, Vol. 110, No. 6, 16.02.2006, p. 2482-2496.

Research output: Contribution to journalArticle

Fialkowski, M, Bishop, KJM, Klajn, R, Smoukov, SK, Campbell, CJ & Grzybowski, BA 2006, 'Principles and implementations of dissipative (dynamic) self-assembly', Journal of Physical Chemistry B, vol. 110, no. 6, pp. 2482-2496. https://doi.org/10.1021/jp054153q
Fialkowski M, Bishop KJM, Klajn R, Smoukov SK, Campbell CJ, Grzybowski BA. Principles and implementations of dissipative (dynamic) self-assembly. Journal of Physical Chemistry B. 2006 Feb 16;110(6):2482-2496. https://doi.org/10.1021/jp054153q
Fialkowski, Marcin ; Bishop, Kyle J M ; Klajn, Rafal ; Smoukov, Stoyan K. ; Campbell, Christopher J. ; Grzybowski, Bartosz A. / Principles and implementations of dissipative (dynamic) self-assembly. In: Journal of Physical Chemistry B. 2006 ; Vol. 110, No. 6. pp. 2482-2496.
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