Abstract
Structural, dynamical and electronic properties of the adducts formed by adsorbing methanol onto size-selected gold clusters are investigated using infrared multiple-photon dissociation spectroscopy of trapped Aun +CH3OH, n≤15, in conjunction with Car-Parrinello calculations. The C-O stretching vibration of the attached sensor molecule changes discontinuously as a function of cluster size, which is traced back to a change in dimensionality of the cluster structure.
| Original language | English |
|---|---|
| Pages (from-to) | 41-46 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 295 |
| Issue number | 1-2 |
| Publication status | Published - Oct 2 1998 |
Fingerprint
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Probing cluster structures with sensor molecules : Methanol adsorbed onto gold clusters. / Rousseau, Roger; Dietrich, G.; Krückeberg, S.; Lützenkirchen, K.; Marx, D.; Schweikhard, L.; Walther, C.
In: Chemical Physics Letters, Vol. 295, No. 1-2, 02.10.1998, p. 41-46.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Probing cluster structures with sensor molecules
T2 - Methanol adsorbed onto gold clusters
AU - Rousseau, Roger
AU - Dietrich, G.
AU - Krückeberg, S.
AU - Lützenkirchen, K.
AU - Marx, D.
AU - Schweikhard, L.
AU - Walther, C.
PY - 1998/10/2
Y1 - 1998/10/2
N2 - Structural, dynamical and electronic properties of the adducts formed by adsorbing methanol onto size-selected gold clusters are investigated using infrared multiple-photon dissociation spectroscopy of trapped Aun +CH3OH, n≤15, in conjunction with Car-Parrinello calculations. The C-O stretching vibration of the attached sensor molecule changes discontinuously as a function of cluster size, which is traced back to a change in dimensionality of the cluster structure.
AB - Structural, dynamical and electronic properties of the adducts formed by adsorbing methanol onto size-selected gold clusters are investigated using infrared multiple-photon dissociation spectroscopy of trapped Aun +CH3OH, n≤15, in conjunction with Car-Parrinello calculations. The C-O stretching vibration of the attached sensor molecule changes discontinuously as a function of cluster size, which is traced back to a change in dimensionality of the cluster structure.
UR - http://www.scopus.com/inward/record.url?scp=0003000256&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0003000256&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0003000256
VL - 295
SP - 41
EP - 46
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-2
ER -