Products of the gas-phase photooxidation reactions of 1 -propanol with OH radicals

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Abstract

An experimental investigation of the hydroxyl radical initiated gas-phase photooxidation of 1-propanol in the presence of NO was carried out in a reaction chamber using gas chromatography mass spectrometry. The products identified in the OH radical reactions of 1-propanol were propionaldehyde and acetaldehyde, with corresponding formation yields of 0.719 ± 0.058 and 0.184 ± 0.030, respectively. Errors represent ± 2σ. The experimental product yields were compared to predictions made using chemical mechanisms.

Original languageEnglish
Pages (from-to)810-818
Number of pages9
JournalInternational Journal of Chemical Kinetics
Volume31
Issue number11
Publication statusPublished - 1999

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

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