Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines

Zachariah M. Heiden, Shentan Chen, Liezel A. Labios, R Morris Bullock, Eric D. Walter, Elizabeth L. Tyson, Michael T. Mock

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7 Citations (Scopus)

Abstract

Protonation of an iron C-H activated complex containing pendant amines in the presence of N2 generated a cis-(H)FeII-N2 complex. Addition of acid protonates the pendant amines. Reduction of the protonated complex results in N2 loss and H2 formation, followed by N2 binding. The origin of H2 formation in this Fe system is compared to proposed mechanisms for H2 loss and N 2 coordination in the E4 state of nitrogenase.

Original languageEnglish
Pages (from-to)1333-1336
Number of pages4
JournalOrganometallics
Volume33
Issue number6
DOIs
Publication statusPublished - Mar 24 2014

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ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Heiden, Z. M., Chen, S., Labios, L. A., Bullock, R. M., Walter, E. D., Tyson, E. L., & Mock, M. T. (2014). Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines. Organometallics, 33(6), 1333-1336. https://doi.org/10.1021/om401089d