Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines

Zachariah M. Heiden; Shentan Chen; Liezel A. Labios; R Morris Bullock; Eric D. Walter; Elizabeth L. Tyson; Michael T. Mock

doi:10.1021/om401089d

Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines

Zachariah M. Heiden, Shentan Chen, Liezel A. Labios, R Morris Bullock, Eric D. Walter, Elizabeth L. Tyson, Michael T. Mock

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Protonation of an iron C-H activated complex containing pendant amines in the presence of N₂ generated a cis-(H)Fe^II-N₂ complex. Addition of acid protonates the pendant amines. Reduction of the protonated complex results in N₂ loss and H₂ formation, followed by N₂ binding. The origin of H₂ formation in this Fe system is compared to proposed mechanisms for H₂ loss and N ₂ coordination in the E₄ state of nitrogenase.

Original language	English
Pages (from-to)	1333-1336
Number of pages	4
Journal	Organometallics
Volume	33
Issue number	6
DOIs	https://doi.org/10.1021/om401089d
Publication status	Published - Mar 24 2014

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ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Inorganic Chemistry

Cite this

Heiden, Z. M., Chen, S., Labios, L. A., Bullock, R. M., Walter, E. D., Tyson, E. L., & Mock, M. T. (2014). Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines. Organometallics, 33(6), 1333-1336. https://doi.org/10.1021/om401089d

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AU - Heiden, Zachariah M.

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AU - Walter, Eric D.

AU - Tyson, Elizabeth L.

AU - Mock, Michael T.

PY - 2014/3/24

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10.1021/om401089d