Abstract
Addition of trifluoromethanesulfonic acid to the heterobimetallic compounds (CO)4ReMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (I) and (CO)4MnMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (II) results in protonation of the metalmetal bond to give cationic compounds with bridging hydrides (III and IV). Deprotonation of III and IV with triethylamine regenerates I and II in high yield.
Original language | English |
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Pages (from-to) | 245-248 |
Number of pages | 4 |
Journal | Journal of Organometallic Chemistry |
Volume | 251 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jul 26 1983 |
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ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry
Cite this
Protonation of metalmetal bonds in heterobimetallic compounds linked by a heterodifunctional ligand. / Casey, Charles P.; Bullock, R Morris.
In: Journal of Organometallic Chemistry, Vol. 251, No. 2, 26.07.1983, p. 245-248.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Protonation of metalmetal bonds in heterobimetallic compounds linked by a heterodifunctional ligand
AU - Casey, Charles P.
AU - Bullock, R Morris
PY - 1983/7/26
Y1 - 1983/7/26
N2 - Addition of trifluoromethanesulfonic acid to the heterobimetallic compounds (CO)4ReMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (I) and (CO)4MnMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (II) results in protonation of the metalmetal bond to give cationic compounds with bridging hydrides (III and IV). Deprotonation of III and IV with triethylamine regenerates I and II in high yield.
AB - Addition of trifluoromethanesulfonic acid to the heterobimetallic compounds (CO)4ReMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (I) and (CO)4MnMo(CO)3[η5-C5H4P(C6H4-p-CH3)2] (II) results in protonation of the metalmetal bond to give cationic compounds with bridging hydrides (III and IV). Deprotonation of III and IV with triethylamine regenerates I and II in high yield.
UR - http://www.scopus.com/inward/record.url?scp=48749143796&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=48749143796&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)99507-X
DO - 10.1016/S0022-328X(00)99507-X
M3 - Article
AN - SCOPUS:48749143796
VL - 251
SP - 245
EP - 248
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 2
ER -