Abstract
The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.
| Original language | English |
|---|---|
| Pages (from-to) | 2785-2787 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 45 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Apr 3 2006 |
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ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
[P6Se12]4- : A phosphorus-rich selenophosphate with low-valent P centers. / Chung, In; Karst, Angela L.; Weliky, David P.; Kanatzidis, Mercouri G.
In: Inorganic Chemistry, Vol. 45, No. 7, 03.04.2006, p. 2785-2787.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - [P6Se12]4-
T2 - A phosphorus-rich selenophosphate with low-valent P centers
AU - Chung, In
AU - Karst, Angela L.
AU - Weliky, David P.
AU - Kanatzidis, Mercouri G
PY - 2006/4/3
Y1 - 2006/4/3
N2 - The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.
AB - The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.
UR - http://www.scopus.com/inward/record.url?scp=33645839317&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33645839317&partnerID=8YFLogxK
U2 - 10.1021/ic0601135
DO - 10.1021/ic0601135
M3 - Article
VL - 45
SP - 2785
EP - 2787
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 7
ER -