[P6Se12]4-

A phosphorus-rich selenophosphate with low-valent P centers

In Chung, Angela L. Karst, David P. Weliky, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.

Original languageEnglish
Pages (from-to)2785-2787
Number of pages3
JournalInorganic Chemistry
Volume45
Issue number7
DOIs
Publication statusPublished - Apr 3 2006

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Alkalies
Phosphorus
Anions
phosphorus
alkalies
anions
synthesis
selenophosphate
decalin

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

[P6Se12]4- : A phosphorus-rich selenophosphate with low-valent P centers. / Chung, In; Karst, Angela L.; Weliky, David P.; Kanatzidis, Mercouri G.

In: Inorganic Chemistry, Vol. 45, No. 7, 03.04.2006, p. 2785-2787.

Research output: Contribution to journalArticle

Chung, In ; Karst, Angela L. ; Weliky, David P. ; Kanatzidis, Mercouri G. / [P6Se12]4- : A phosphorus-rich selenophosphate with low-valent P centers. In: Inorganic Chemistry. 2006 ; Vol. 45, No. 7. pp. 2785-2787.
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