[P6Se12]4-: A phosphorus-rich selenophosphate with low-valent P centers

In Chung; Angela L. Karst; David P. Weliky; Mercouri G. Kanatzidis

doi:10.1021/ic0601135

[P₆Se₁₂]^4-: A phosphorus-rich selenophosphate with low-valent P centers

In Chung, Angela L. Karst, David P. Weliky, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article

23 Citations (Scopus)

Abstract

The new selenophosphate Rb₄P₆Se₁₂ features the trans-decalin-like, [P₆Se₁₂]^4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P²⁺ and P⁴⁺ centers. The synthesis of Rb₄P₆Se₁₂ was accomplished with the reductive addition of P to RbPSe₆ and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.

Original language	English
Pages (from-to)	2785-2787
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	7
DOIs	https://doi.org/10.1021/ic0601135
Publication status	Published - Apr 3 2006

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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Chung, I., Karst, A. L., Weliky, D. P., & Kanatzidis, M. G. (2006). [P₆Se₁₂]^4-: A phosphorus-rich selenophosphate with low-valent P centers. Inorganic Chemistry, 45(7), 2785-2787. https://doi.org/10.1021/ic0601135

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abstract = "The new selenophosphate Rb4P6Se12 features the trans-decalin-like, [P6Se12]4- anion, a phosphorus-rich species that possesses three parallel P-P bonds and formally P2+ and P4+ centers. The synthesis of Rb4P6Se12 was accomplished with the reductive addition of P to RbPSe6 and represents an interesting example of how alkali chalcophosphates can serve as starting materials to produce new compounds under mild reaction conditions.",

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