Putting chromium on the map for N2 reduction

Production of hydrazine and ammonia. A study of: Cis -M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes

Jonathan D. Egbert, Molly O'Hagan, Eric Wiedner, R Morris Bullock, Nicholas A. Piro, W. Scott Kassel, Michael T. Mock

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The first complete structurally and spectroscopically characterized series of isostructural Group 6 N2 complexes is reported. Protonolysis experiments on cis-[M(N2)2(PEtNRPEt)2] (M = Cr, Mo, W; R = 2,6-difluorobenzyl) reveal that only Cr affords N2H5 + and NH4 + from the reduction of the N2 ligands.

Original languageEnglish
Pages (from-to)9343-9346
Number of pages4
JournalChemical Communications
Volume52
Issue number60
DOIs
Publication statusPublished - 2016

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hydrazine
Hydrazine
Chromium
Ammonia
Ligands
Experiments

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Putting chromium on the map for N2 reduction : Production of hydrazine and ammonia. A study of: Cis -M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes. / Egbert, Jonathan D.; O'Hagan, Molly; Wiedner, Eric; Bullock, R Morris; Piro, Nicholas A.; Kassel, W. Scott; Mock, Michael T.

In: Chemical Communications, Vol. 52, No. 60, 2016, p. 9343-9346.

Research output: Contribution to journalArticle

Egbert, Jonathan D. ; O'Hagan, Molly ; Wiedner, Eric ; Bullock, R Morris ; Piro, Nicholas A. ; Kassel, W. Scott ; Mock, Michael T. / Putting chromium on the map for N2 reduction : Production of hydrazine and ammonia. A study of: Cis -M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes. In: Chemical Communications. 2016 ; Vol. 52, No. 60. pp. 9343-9346.
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