[pyH+]2[CdNb2(py)4O 2F10]2-

Paramasivan Halasyamani, Michael J. Willis, Kevin R. Heier, Charlotte L. Stern, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A new CdII/Nbv compound, bis(pyridinium) decafluoro-2κ5F,3κ5 F-di-μ-oxo-1:2κ2O;1:3κ 2O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)2[CdNb2F10O 2(C5H5-N)4], has been synthesized. The complex contains [CdNb2(Py)4F10O2]2- anions (py is pyridine) linked via the pyridinium cation through N - H+⋯F hydrogen bonding. The anion is composed of two [NbF5O1/2]- octahedra connected by O2- to a central [Cd(py)4O2/2] octahedron.

Original languageEnglish
Pages (from-to)2491-2493
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number10
Publication statusPublished - Oct 15 1996

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Pyridinium Compounds
Anions
pyridines
anions
Hydrogen Bonding
Cations
Hydrogen bonds
cations
hydrogen
pyridine

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Halasyamani, P., Willis, M. J., Heier, K. R., Stern, C. L., & Poeppelmeier, K. R. (1996). [pyH+]2[CdNb2(py)4O 2F10]2-. Acta Crystallographica Section C: Crystal Structure Communications, 52(10), 2491-2493.

[pyH+]2[CdNb2(py)4O 2F10]2-. / Halasyamani, Paramasivan; Willis, Michael J.; Heier, Kevin R.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 10, 15.10.1996, p. 2491-2493.

Research output: Contribution to journalArticle

Halasyamani, P, Willis, MJ, Heier, KR, Stern, CL & Poeppelmeier, KR 1996, '[pyH+]2[CdNb2(py)4O 2F10]2-', Acta Crystallographica Section C: Crystal Structure Communications, vol. 52, no. 10, pp. 2491-2493.
Halasyamani P, Willis MJ, Heier KR, Stern CL, Poeppelmeier KR. [pyH+]2[CdNb2(py)4O 2F10]2-. Acta Crystallographica Section C: Crystal Structure Communications. 1996 Oct 15;52(10):2491-2493.
Halasyamani, Paramasivan ; Willis, Michael J. ; Heier, Kevin R. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / [pyH+]2[CdNb2(py)4O 2F10]2-. In: Acta Crystallographica Section C: Crystal Structure Communications. 1996 ; Vol. 52, No. 10. pp. 2491-2493.
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abstract = "A new CdII/Nbv compound, bis(pyridinium) decafluoro-2κ5F,3κ5 F-di-μ-oxo-1:2κ2O;1:3κ 2O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)2[CdNb2F10O 2(C5H5-N)4], has been synthesized. The complex contains [CdNb2(Py)4F10O2]2- anions (py is pyridine) linked via the pyridinium cation through N - H+⋯F hydrogen bonding. The anion is composed of two [NbF5O1/2]- octahedra connected by O2- to a central [Cd(py)4O2/2] octahedron.",
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AU - Halasyamani, Paramasivan

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AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R

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