Raman scattering from nonequilibrium molecular conduction junctions

Michael Galperin, Mark A. Ratner, Abraham Nitzan

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Raman scattering is a potentially important probe of structure, dynamics, and thermal properties of single-molecule conduction junctions. We combine a nonequilibrium Green's function description of the junction with a generalized scattering theory of the Raman process, which provides the first theoretical description of Raman scattering from such systems. The voltage dependence of the Raman flux shows a characteristic behavior at the conductance threshold resulting from (a) partial populations in the ground and excited molecular levels that give rise to two scattering pathways as well as interference between them and (b) junction heating that affects the Raman intensities. Comparing "effective temperatures" obtained from Raman scattering and heat balance serves to establish the integrity of this concept for nonequilibrium junctions.

Original languageEnglish
Pages (from-to)758-762
Number of pages5
JournalNano letters
Volume9
Issue number2
DOIs
Publication statusPublished - Feb 11 2009

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

Fingerprint Dive into the research topics of 'Raman scattering from nonequilibrium molecular conduction junctions'. Together they form a unique fingerprint.

  • Cite this