Abstract
Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO 2, N 2 and CH 4 with Zn(bdc)(ted) 0.5.
| Original language | English |
|---|---|
| Title of host publication | Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies |
| Pages | 1-5 |
| Number of pages | 5 |
| DOIs | |
| Publication status | Published - Dec 1 2011 |
| Event | 2011 MRS Spring Meeting - San Francisco, CA, United States Duration: Apr 25 2011 → Apr 29 2011 |
Publication series
| Name | Materials Research Society Symposium Proceedings |
|---|---|
| Volume | 1334 |
| ISSN (Print) | 0272-9172 |
Other
| Other | 2011 MRS Spring Meeting |
|---|---|
| Country | United States |
| City | San Francisco, CA |
| Period | 4/25/11 → 4/29/11 |
ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
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Cite this
Nijem, N., Roodenko, K., Zhao, Y., Li, J., & Chabal, Y. J. (2011). Raman spectroscopy for probing guest-host interactions in metal organic frameworks. In Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies (pp. 1-5). (Materials Research Society Symposium Proceedings; Vol. 1334). https://doi.org/10.1557/opl.2011.1311