Raman spectroscopy for probing guest-host interactions in metal organic frameworks

Nour Nijem, Katy Roodenko, Yonggang Zhao, Jing Li, Yves J. Chabal

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO 2, N 2 and CH 4 with Zn(bdc)(ted) 0.5.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium Proceedings
Pages1-5
Number of pages5
Volume1334
DOIs
Publication statusPublished - 2011
Event2011 MRS Spring Meeting - San Francisco, CA, United States
Duration: Apr 25 2011Apr 29 2011

Other

Other2011 MRS Spring Meeting
CountryUnited States
CitySan Francisco, CA
Period4/25/114/29/11

Fingerprint

Raman spectroscopy
Metals
Molecules
Carbon Monoxide
metals
interactions
molecules
methylidyne
probes

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Nijem, N., Roodenko, K., Zhao, Y., Li, J., & Chabal, Y. J. (2011). Raman spectroscopy for probing guest-host interactions in metal organic frameworks. In Materials Research Society Symposium Proceedings (Vol. 1334, pp. 1-5) https://doi.org/10.1557/opl.2011.1311

Raman spectroscopy for probing guest-host interactions in metal organic frameworks. / Nijem, Nour; Roodenko, Katy; Zhao, Yonggang; Li, Jing; Chabal, Yves J.

Materials Research Society Symposium Proceedings. Vol. 1334 2011. p. 1-5.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Nijem, N, Roodenko, K, Zhao, Y, Li, J & Chabal, YJ 2011, Raman spectroscopy for probing guest-host interactions in metal organic frameworks. in Materials Research Society Symposium Proceedings. vol. 1334, pp. 1-5, 2011 MRS Spring Meeting, San Francisco, CA, United States, 4/25/11. https://doi.org/10.1557/opl.2011.1311
Nijem N, Roodenko K, Zhao Y, Li J, Chabal YJ. Raman spectroscopy for probing guest-host interactions in metal organic frameworks. In Materials Research Society Symposium Proceedings. Vol. 1334. 2011. p. 1-5 https://doi.org/10.1557/opl.2011.1311
Nijem, Nour ; Roodenko, Katy ; Zhao, Yonggang ; Li, Jing ; Chabal, Yves J. / Raman spectroscopy for probing guest-host interactions in metal organic frameworks. Materials Research Society Symposium Proceedings. Vol. 1334 2011. pp. 1-5
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