Abstract
Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO 2, N 2 and CH 4 with Zn(bdc)(ted) 0.5.
| Original language | English |
|---|---|
| Title of host publication | Materials Research Society Symposium Proceedings |
| Pages | 1-5 |
| Number of pages | 5 |
| Volume | 1334 |
| DOIs | |
| Publication status | Published - 2011 |
| Event | 2011 MRS Spring Meeting - San Francisco, CA, United States Duration: Apr 25 2011 → Apr 29 2011 |
Other
| Other | 2011 MRS Spring Meeting |
|---|---|
| Country | United States |
| City | San Francisco, CA |
| Period | 4/25/11 → 4/29/11 |
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ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Mechanical Engineering
- Mechanics of Materials
Cite this
Raman spectroscopy for probing guest-host interactions in metal organic frameworks. / Nijem, Nour; Roodenko, Katy; Zhao, Yonggang; Li, Jing; Chabal, Yves J.
Materials Research Society Symposium Proceedings. Vol. 1334 2011. p. 1-5.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Raman spectroscopy for probing guest-host interactions in metal organic frameworks
AU - Nijem, Nour
AU - Roodenko, Katy
AU - Zhao, Yonggang
AU - Li, Jing
AU - Chabal, Yves J.
PY - 2011
Y1 - 2011
N2 - Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO 2, N 2 and CH 4 with Zn(bdc)(ted) 0.5.
AB - Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO 2, N 2 and CH 4 with Zn(bdc)(ted) 0.5.
UR - http://www.scopus.com/inward/record.url?scp=84860596780&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84860596780&partnerID=8YFLogxK
U2 - 10.1557/opl.2011.1311
DO - 10.1557/opl.2011.1311
M3 - Conference contribution
AN - SCOPUS:84860596780
SN - 9781618395306
VL - 1334
SP - 1
EP - 5
BT - Materials Research Society Symposium Proceedings
ER -