Raman spectroscopy for probing guest-host interactions in metal organic frameworks

Nour Nijem; Katy Roodenko; Yonggang Zhao; Jing Li; Yves J. Chabal

doi:10.1557/opl.2011.1311

Raman spectroscopy for probing guest-host interactions in metal organic frameworks

Nour Nijem, Katy Roodenko, Yonggang Zhao, Jing Li, Yves J. Chabal

Rutgers University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Spectroscopic techniques such as IR and Raman are very powerful to understand guest-host interactions. Although these techniques are complementary, Raman spectroscopy has not been widely implemented as a tool to characterize these interactions. This study illustrates the use of Raman spectroscopy not only to probe the interactions experienced by a guest molecule but also to detect structural changes occurring in the framework upon loading. Weak interactions of adsorbed molecules with the framework are reflected in frequency and intensity variations in both Raman and IR absorption lines, as shown for the case of CO ₂, N ₂ and CH ₄ with Zn(bdc)(ted) _0.5.

Original language	English
Title of host publication	Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies
Pages	1-5
Number of pages	5
DOIs	https://doi.org/10.1557/opl.2011.1311
Publication status	Published - Dec 1 2011
Event	2011 MRS Spring Meeting - San Francisco, CA, United States Duration: Apr 25 2011 → Apr 29 2011

Publication series

Name	Materials Research Society Symposium Proceedings
Volume	1334
ISSN (Print)	0272-9172

Other

Other	2011 MRS Spring Meeting
Country	United States
City	San Francisco, CA
Period	4/25/11 → 4/29/11

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ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Cite this

Nijem, N., Roodenko, K., Zhao, Y., Li, J., & Chabal, Y. J. (2011). Raman spectroscopy for probing guest-host interactions in metal organic frameworks. In Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies (pp. 1-5). (Materials Research Society Symposium Proceedings; Vol. 1334). https://doi.org/10.1557/opl.2011.1311

Raman spectroscopy for probing guest-host interactions in metal organic frameworks. / Nijem, Nour; Roodenko, Katy; Zhao, Yonggang; Li, Jing; Chabal, Yves J.

Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies. 2011. p. 1-5 (Materials Research Society Symposium Proceedings; Vol. 1334).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Nijem, N, Roodenko, K, Zhao, Y, Li, J & Chabal, YJ 2011, Raman spectroscopy for probing guest-host interactions in metal organic frameworks. in Recent Developments in Materials for Hydrogen Storage and Carbon-Capture Technologies. Materials Research Society Symposium Proceedings, vol. 1334, pp. 1-5, 2011 MRS Spring Meeting, San Francisco, CA, United States, 4/25/11. https://doi.org/10.1557/opl.2011.1311

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Access to Document

10.1557/opl.2011.1311