Abstract
The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.
| Original language | English |
|---|---|
| Pages (from-to) | 7921-7930 |
| Number of pages | 10 |
| Journal | Journal of Chemical Physics |
| Volume | 111 |
| Issue number | 17 |
| Publication status | Published - Nov 1 1999 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Reaction dynamics of O(1D) + HD. I. the insertion pathway. / Hsu, Yen Tsung; Liu, Kopin; Pederson, Lisa A.; Schatz, George C.
In: Journal of Chemical Physics, Vol. 111, No. 17, 01.11.1999, p. 7921-7930.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Reaction dynamics of O(1D) + HD. I. the insertion pathway
AU - Hsu, Yen Tsung
AU - Liu, Kopin
AU - Pederson, Lisa A.
AU - Schatz, George C
PY - 1999/11/1
Y1 - 1999/11/1
N2 - The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.
AB - The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.
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UR - http://www.scopus.com/inward/citedby.url?scp=0001033010&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0001033010
VL - 111
SP - 7921
EP - 7930
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 17
ER -