Abstract
The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.
| Original language | English |
|---|---|
| Pages (from-to) | 7921-7930 |
| Number of pages | 10 |
| Journal | Journal of Chemical Physics |
| Volume | 111 |
| Issue number | 17 |
| Publication status | Published - Nov 1 1999 |
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
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Hsu, Y. T., Liu, K., Pederson, L. A., & Schatz, G. C. (1999). Reaction dynamics of O(1D) + HD. I. the insertion pathway. Journal of Chemical Physics, 111(17), 7921-7930.