Reaction dynamics of O(1D) + HD. I. the insertion pathway

Yen Tsung Hsu, Kopin Liu, Lisa A. Pederson, George C Schatz

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Abstract

The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.

Original languageEnglish
Pages (from-to)7921-7930
Number of pages10
JournalJournal of Chemical Physics
Volume111
Issue number17
Publication statusPublished - Nov 1 1999

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ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Hsu, Y. T., Liu, K., Pederson, L. A., & Schatz, G. C. (1999). Reaction dynamics of O(1D) + HD. I. the insertion pathway. Journal of Chemical Physics, 111(17), 7921-7930.