Reaction dynamics of O(1D) + HD. I. the insertion pathway

Yen Tsung Hsu, Kopin Liu, Lisa A. Pederson, George C Schatz

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

The doubly differential cross sections (angle and speed) for the reactions O(1D) + HD→OH(OD) + D(H) at Ec=2.05 kcal/mol were directly mapped out using the Doppler-selected time-of-flight technique in a crossed-beam experiment. Except for the previously noted discrepancy in the H/D isotope branching ratio, good agreement with QCT (quasiclassical trajectory) results on a high quality ab initio surface are found for all dynamical features, including the product angular and translational energy distributions and the very detailed angle-specific translational energy release.

Original languageEnglish
Pages (from-to)7921-7930
Number of pages10
JournalJournal of Chemical Physics
Volume111
Issue number17
Publication statusPublished - Nov 1 1999

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Isotopes
insertion
Trajectories
energy distribution
isotopes
Experiments
trajectories
cross sections
products
energy

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Hsu, Y. T., Liu, K., Pederson, L. A., & Schatz, G. C. (1999). Reaction dynamics of O(1D) + HD. I. the insertion pathway. Journal of Chemical Physics, 111(17), 7921-7930.

Reaction dynamics of O(1D) + HD. I. the insertion pathway. / Hsu, Yen Tsung; Liu, Kopin; Pederson, Lisa A.; Schatz, George C.

In: Journal of Chemical Physics, Vol. 111, No. 17, 01.11.1999, p. 7921-7930.

Research output: Contribution to journalArticle

Hsu, YT, Liu, K, Pederson, LA & Schatz, GC 1999, 'Reaction dynamics of O(1D) + HD. I. the insertion pathway', Journal of Chemical Physics, vol. 111, no. 17, pp. 7921-7930.
Hsu, Yen Tsung ; Liu, Kopin ; Pederson, Lisa A. ; Schatz, George C. / Reaction dynamics of O(1D) + HD. I. the insertion pathway. In: Journal of Chemical Physics. 1999 ; Vol. 111, No. 17. pp. 7921-7930.
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