Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Yasuo Matsubara, Sean E. Hightower, Jinzhu Chen, David Grills, Dmitry Polyansky, James Muckerman, Koji Tanaka, Etsuko Fujita

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The reactivity of a rhenium complex containing an NAD+ model ligand was examined toward photochemical formation of the corresponding NADH-like dihydro form of the complex and electrochemical CO2 reduction. The hydricity of the NADH-like complex was estimated by a thermodynamic cycle and reaction with Ph3C+.

Original languageEnglish
Pages (from-to)728-730
Number of pages3
JournalChemical Communications
Volume50
Issue number6
DOIs
Publication statusPublished - Jan 21 2014

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Rhenium
Carbon Monoxide
NAD
Ligands
Thermodynamics

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction. / Matsubara, Yasuo; Hightower, Sean E.; Chen, Jinzhu; Grills, David; Polyansky, Dmitry; Muckerman, James; Tanaka, Koji; Fujita, Etsuko.

In: Chemical Communications, Vol. 50, No. 6, 21.01.2014, p. 728-730.

Research output: Contribution to journalArticle

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AU - Tanaka, Koji

AU - Fujita, Etsuko

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